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Oxidized cobalt complexes of salicylaldehydes

Synthesis, structural and thermal investigation

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Abstract

Cobalt(III) complexes of 2,2′-dipyridylamine (dpamH) and the ligands salicylaldehyde (X-saloH) and their corresponding salicylic acids (X-salicylato), where X = CH3, Cl and Br, under the general formula [Co(X-salo)(X-salicylato)(dpamH)] (1–3), were synthesized in situ by slow oxidation in air of ethanolic solutions of the complexes [Co(5-X-salo)2(dpamH)]. The new compounds were characterized by physicochemical methods and by spectroscopy (IR, 1H-NMR and UV–Vis). The octahedral geometry around Co3+ ion and the bidentate chelating mode of the salicylaldehydato anion (X-salo−) and the salicylato di-anion (X-salicylato2−) were proved by single-crystal X-ray diffraction analysis for the complex [Co(5-CH3-salo)(5-CH3-salicylato)(dpamH)] (1). The variable-temperature (76–303 K) magnetic susceptibility measurements showed a diamagnetic nature of the complexes, in accordance with their molecular structure. The simultaneous TG/DTG–DTA technique was used to analyze their thermal behavior under inert and/or oxygen atmosphere, with particular attention to determine their thermal degradation pathways, which was found to have a multi-step nature, accompanied by the release of the ligand molecules.

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Acknowledgements

The authors would like to thank Professor Evdoxia Coutouli-Argyropoulou (Aristotle University of Thessaloniki) for recording the 1H–NMR spectra.

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Authors and Affiliations

  1. Laboratory of Inorganic Chemistry, Department of Chemistry, Aristotle University of Thessaloniki, 54 124, Thessaloniki, Greece

    Maria Lalia-Kantouri, Christos Papadopoulos & Antonios Hatzidimitriou

  2. Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, Sq. Maria Curie- Skłodowska 2, 20-031, Lublin, Poland

    Beata Cristóvão & Wieslawa Ferenc

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  1. Maria Lalia-Kantouri
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  2. Christos Papadopoulos
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Correspondence to Maria Lalia-Kantouri.

Electronic supplementary material

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10973_2016_5727_MOESM1_ESM.pdf

Detailed crystal data and structure refinement for complex [Co(5–CH3–salo)(5–CH3–salicylato) (dpamH)]. H2O (1) have been deposited with the Cambridge Crystallographic Data Centre under, No CCDC 1472312. Copies of this information may be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge, CB2 IEZ, UK (fax: +44-1223-336033; e-mail: deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk). (PDF 160 kb)

Supplementary material 1 (CIF 30 kb)

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Lalia-Kantouri, M., Papadopoulos, C., Hatzidimitriou, A. et al. Oxidized cobalt complexes of salicylaldehydes. J Therm Anal Calorim 126, 1579–1590 (2016). https://doi.org/10.1007/s10973-016-5727-9

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