Abstract
In this work, the synthesis of the Li2TiSiO5 photoluminescent compound, obtained from a stoichiometric mixture of Li2CO3, SiO2 and TiO2 nanoparticles, was investigated by two different routes named route I (melting and quenching) and route II (solid-state reaction). In the route I, the raw materials were melted (1550 °C/2 h) and cooled into water. Subsequently, the solidified product was milled (30 min) in a high-energy mill. In the route II, the raw materials were directly milled (10 min). The obtained powders, from both routes, were heat treated at different temperatures (900–1000 °C/60 min) and then subjected to crystallographic (XRD) and thermal (DSC) analyses in order to investigate the resulting structure and the associated physical–chemical reactions. The results showed that it is possible to obtain the Li2TiSiO5 compound from both synthesis routes but, apparently, the route I seems to be more appropriated to obtain the Li2TiSiO5 compound and to demonstrate the photoluminescence phenomena with and even without thermal treatment.
Similar content being viewed by others
References
Valeur B. Molecular fluorescence: principles and applications. Weinheim: Wiley VCH; 2009.
Lucena PR, Pontes FM, Pinheiro CD, Longo E, Pizani PS, Lázaro S, Souza AG, Santos IMG. Photoluminescence in disordered materials. Ceramica. 2004. doi:10.1590/S0366-69132004000200011.
Richerson DW. Modern ceramic engineering: properties, processing, and use in design. 2nd ed. Nova York: Marcel Dekker Press; 1992.
Bouma B, Blasse G. Dependence of luminescence of titanates on their crystal structure. J Phys Chem Solids. 1995. doi:10.1016/0022-3697(94)00174-X.
Orhan E, Albarici VC, Escote MT, Machado MAC, Pizani PS, Leite ER, Sambrano JR, Varela JA, Longo E. A DFT rationalization of the room temperature photoluminescence of Li2TiSiO5. Chem Phys Lett. 2004. doi:10.1016/j.cplett.2004.09.091.
Bastow TJ, Botton GA, Etheridge J, Smith ME, Whitfield HJ. A study of Li2TiOSiO4 and Li2TiOGeO4 by X-ray powder and electron single-crystal diffraction. Acta Crystallogr. 1999. doi:10.1107/S0108767398006990.
Porto SL, Cassia-Santos MR, Santos IMG, Lima SJG, Soledade LEB, Souza AG, Paskocimas CA, Longo E. Synthesis of CaxSr1−xWO4 by the polymeric precursor method. J Therm Anal Calorim. 2005;79:401–6.
Ziadi A, Thiele G, Elouad B. The crystal structure of Li2TiSiO5. J Solid State Chem. 1994. doi:10.1006/jssc.1994.1079.
Izquierdo G, West AR. Melting behavior of Li2TiSiO5. Mater Sci. 1981;16:219–21.
Leite ER, Carreño NLV, Santos LPS, Rangel JH, Soledade LEB, Longo E, Campos CEM, Lanciotti F Jr, Pizani PS, Varela JA. Photoluminescence in amorphous TiO2–PbO systems. Appl Phys A. 2001;73:567–9.
Pontes FM, Pinheiro CD, Longo E, Leite ER, Lazaro SR, Varela JA, Pizani PS, Boschi TM, Lanciotti F Jr. The role of network modifiers in the creation of photoluminescence in CaTiO3. Mater Chem Phys. 2002;78:227–33.
Soledade LEB, Longo E, Leite ER, Pontes FM, Lanciotti Jr. F, Campos CEM, Pizani OS, Varela JA. Photoluminescence at room temperature in amorphous strontium titanate—the influence of the receptor-type dopants (Portuguese). In: Proceedings of the 47th annual meeting of the Brazilian Ceramic Society, 2003. https://www.ipen.br/biblioteca/cd/cbc/2003/artigos/47cbc-11-28.doc. Accessed 23 Oct 2015.
Acknowledgements
The authors are gratefully by the financial support provided by Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq, Brazil) and Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES, Brazil).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Souza, M.T., Cesconeto, F.R., Arcaro, S. et al. Synthesis and characterization of Li2TiSiO5 obtained by melting and solid-state reaction. J Therm Anal Calorim 127, 463–467 (2017). https://doi.org/10.1007/s10973-016-5396-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-016-5396-8