Skip to main content
SpringerLink
Log in

A tridentate (O, N, O) donor Schiff base zinc(II) nano complex

synthesis, characterization, and favorable conditions for thin film assembly

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

A nano tridentate (O, N, O) donor Schiff base derived from salicylaldehyde and o-aminophenol (o-AP), 2-[[(2-hydroxyphenyl)imino]methyl]phenol (PIMP), and its nano Zinc(II) complex thin films, [Zn(PIMP)(H2O)]; ZnSB-1, are synthesized via Layer-by-Layer (LbL) self-assembly method at ambient temperatures. Elemental and metal analyses confirm a (1:1) ligand to metal stoichiometric ratio of ZnSB-1 nano complex. Scanning electron microscopy elucidates the nano nature of the self-assembled materials. Powder X-ray diffraction and SEM revealed an excellent crystallized nano ZnSB-1 complex. Fourier transform infrared spectra reveal the coordination nature between Zinc(II) and PIMP ligand in nano ZnSB-1 complex. Electron impact mass spectra and thermogravimetric analysis (TG) studies confirm the chemical structure of LbL self-assembled nano materials. TG/DTG studies also show an increase in the thermal stability of the ZnSB-1 nano complex over its nano PIMP precursor. The favorable conditions for ZnSB-1 nano thin film assembly are focused and studied through tuning a number of different parameters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Liu L, Shao MW, Wang X-H. One-dimensional organic photoconductive nanoribbons built on Zn–Schiff base complex. J Solid State Chem. 2010;183:590–4.

    Article  CAS  Google Scholar 

  2. Haggag SMS, Farag AAM, Abdelrafea M. Spectral, thermal and optical-electrical properties of the layer-by-layer deposited thin film of nano Zn(II)-8-hydroxy-5-nitrosoquinolate complex. Spectrochim Acta Part A. 2013;110:14–9.

    Article  CAS  Google Scholar 

  3. Deshmukh PK, Ketan P, Ramani KP, Singh SS, Tekade AR, Chatap VK, Patil GB, Bari SB. Stimuli-sensitive layer-by-layer (LbL) self-assembly systems: targeting and biosensory applications. J Control Release. 2013;166:294–306.

    Article  CAS  Google Scholar 

  4. Xiong X, Duan J, Wang Y, Yu Zhaoju. Novel hierarchical microparticles super-assembled from nanoparticles with the induction of casein micelle. J Nanopart Res. 2013;15:1870–80.

    Article  Google Scholar 

  5. Xu T, Zhong Y, liu Y, Yu H, Mao Z. Flammability properties of PI fabric coated with montmorillonite. J Therm Anal Calorim. 2013;111:27–33.

    Article  CAS  Google Scholar 

  6. Tang Q, Cai H, Yuan S, Wang X. Percolation effect and thermoplasticity of conducting [poly(acrylic acid)/C16TAB-modified graphene oxide]n multilayer films. J Mater Sci. 2013;48:1843–51.

    Article  CAS  Google Scholar 

  7. Wang L, Zhang T, Yan H, Peng 彭懋 M, Fang Z, Li Y, Hao W. Flame-retardant coating by alternate assembly of poly(vinylphosphonic acid) and polyethylenimine for ramie fabrics. Chin J Polym Sci. 2014;32:305–14.

    Article  CAS  Google Scholar 

  8. Afkhami A, Khajavi F, Khanmohmmadi H. Spectrophotometric determination of acidity and tautomeric constants and hydrogen bonding strength for a new Schiff base using hard modeling and multivariate curve resolution alternative least squares methods. Analytica Chim Acta. 2009;634:180–5.

    Article  CAS  Google Scholar 

  9. Guoliang Z, Yunlong F, Yihang W. Syntheses, crystal structures and kinetic mechanisms of thermal decomposition of rare earth complexes with Schiff base derived from o-vanillin and p-tohidine. J Rare earth. 2006;24:268–75.

    Article  Google Scholar 

  10. Ambrozini B, Dockal ER, Cavalheiro ÉTG. Thermal behavior of tetradentate Schiff base chromium(III) complexes. J Therm Anal Calorim. 2014;115:979–86.

    Article  CAS  Google Scholar 

  11. Li H, You ZL, Zhang CL, Yang M, Gao LN, Wang L. Zinc and thiocyanate-mediated oxazolidine ring formation in a trinuclear zinc(II) complex: synthesis, structure, and properties. Inorg Chem Commun. 2013;29:118–22.

    Article  Google Scholar 

  12. da Silva CM, da Silva DL, Modolo LV, Alves RB, de Resende MA, Matrins CVB, de Fatima A. Schiff bases: a short review of their antimicrobial activities. J Adv Res. 2011;2:1–8.

    Article  Google Scholar 

  13. Golcu A, Tumer M, Demirelli H, Wheatley RA. Cd(II) and Cu(II) complexes of polydentate Schiff base ligands: synthesis, characterization, properties and biological activity. Inorganica Chim Acta. 2005;358:1785–97.

    Article  CAS  Google Scholar 

  14. Saheb V, Sheikhshoaie I. A new Schiff base compound N,N-(2,2-dimetylpropane)-bis(dihydroxylacetophenone): synthesis, experimental and theoretical studies on its crystal structure, FTIR, UV–visible, 1H NMR and 13C NMR spectra. Spectrochim Acta Part A. 2011;81:144–50.

    Article  CAS  Google Scholar 

  15. Macho V, Kralik Milan, Hudec Jozef, Cinglova Jarmila. One stage preparation of Schiff’s bases from nitroarenes, aldehydes and carbon monoxide at presence of water. J Mol Catal A. 2004;209:69–73.

    Article  CAS  Google Scholar 

  16. Khalaji AD, Nikookar M, Das D. Co(III), Ni(II), and Cu(II) complexes of bidentate N, O-donor Schiff base ligand derived from 4-methoxy-2-nitroaniline and salicylaldehyde. J Therm Anal Calorim. 2014;115:409–15.

    Article  CAS  Google Scholar 

  17. Tantaru G, Dorneanu V, Stan M. Schiff bis bases: Analytical reagents. II. Spectrophotometric determination of manganese from pharmaceutical forms. J Pharmaceut Biomed. 2002;27:827–32.

    Article  CAS  Google Scholar 

  18. Emara AAA. Structural, spectral and biological studies of binuclear tetradentate metal complexes of N3O Schiff base ligand synthesized from 4,6-diacetylresorcinol and diethylenetriamine. Spectrochim Acta Part A. 2010;77:117–25.

    Article  Google Scholar 

  19. Taylor MK, Reglinski J, Wallace D. Coordination geometry of tetradentate Schiff base nickel complexes: the effects of donors, backbone length and hydrogenation. Polyhedron. 2004;23:3201–9.

    Article  CAS  Google Scholar 

  20. Bhardwaj VK, Hundal MS, Corbella M, Gomez V, Hundal G. Salicylaldimine Schiff bases—generation of self-assembled and chiral complexes with Ni(II) and Zn(II) ions. Polyhedron. 2012;38:224–34.

    Article  CAS  Google Scholar 

  21. Kianfar AH, Paliz M, Roushani M, Shamsipur M. Synthesis, spectroscopy, electrochemistry and thermal study of vanadyl tridentate Schiff base complexes. Spectrochim Acta Part A. 2011;82:44–8.

    Article  CAS  Google Scholar 

  22. Shahabadi N, Kashanian S, Darabi F. DNA binding and DNA cleavage studies of a water soluble cobalt(II) complex containing dinitrogen Schiff base ligand: the effect of metal on the mode of binding. European J Med Chem. 2010;45:4239–45.

    Article  CAS  Google Scholar 

  23. Chattopadhyay S, Chakraborty P, Drew MGB, Ghosh A. Nickel(II) complexes of terdentate or symmetrical tetradentate Schiff bases: evidence of the influence of the counter anions in the hydrolysis of the imine bond in Schiff base complexes. Inorganica Chim Acta. 2009;362:502–8.

    Article  CAS  Google Scholar 

  24. Ray A, Rosair GM, Pilet G, Dede B, Gomez-Garcia CJ, Signorella S, Bellu S, Mitra S. Preferential azido bridging regulating the structural aspects in cobalt(III) and copper(II)–Schiff base complexes: syntheses, magnetostructural correlations and catalytic studies. Inorganica Chim Acta. 2005;375:20–30.

    Article  Google Scholar 

  25. Singh AK, Pandey OP, Sengupta SK. Synthesis, spectral characterization and biological activity of zinc(II) complexes with 3-substituted-4-amino-5-hydrazino-1, 2, 4-triazole Schiff bases. Spectrochim Acta Part A. 2012;85:1–6.

    Article  CAS  Google Scholar 

  26. Naiya S, Sarkar B, Song Y, Ianelli S, Drew MGB, Ghosh A. Carbonyl compound dependent hydrolysis of mono-condensed Schiff bases: a trinuclear Schiff base complex and a mononuclear mixed-ligand ternary complex of copper(II). Inorganica Chim Acta. 2010;363:2488–95.

    Article  CAS  Google Scholar 

  27. Zayed EM, Zayed MA, Hindy AMM. Thermal and spectroscopic investigation of novel Schiff base, its metal complexes, and their biological activities. J Therm Anal Calorim. 2014;116:391–400.

    Article  CAS  Google Scholar 

  28. Zianna A, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Zinc complexes of salicylaldehydes: synthesis, characterization and DNA-binding properties. J Inorg Biochem. 2013;127:116–26.

    Article  CAS  Google Scholar 

  29. Katsoulakou E, Dermitzaki D, Konidaris KF, Moushi EE, Raptopoulou CP, Psycharis V, Tasiopoulos AJ, Bekiari V, Manessi-Zoupa E, Perlepes SP, Stamatatos TC. Hexanuclear zinc(II) carboxylate complexes from the use of pyridine-2,6-dimethanol: Synthetic, structural and photoluminescence studies. Polyhedron. 2013;52:467–75.

    Article  CAS  Google Scholar 

  30. Umayal M, Mugesh G. Metallo-β-lactamase and phosphotriesterase activities of some zinc(II) complexes. Inorganica Chim Acta. 2011;372:353–61.

    Article  CAS  Google Scholar 

  31. Homzová K, Győryová K, Bujdošová Z, Hudecová D, Ganajová M, Vargová Z, Kovářová J. Synthesis, thermal, spectral and biological properties of zinc(II) 4-hydroxybenzoate complexes. J Therm Anal Calorim. 2014;116:77–91.

    Article  Google Scholar 

  32. Oberda K, Deperasin´ska I, Nizhnik YP, Szemik-Hojniak A. A novel complex of zinc tetraphenylporphyrin with two dioxane molecules in a rare attachment. Polyhedron. 2013;51:61–9.

    Article  CAS  Google Scholar 

  33. Shixaliyeva NQ, Maharramova AM, Gurbanov AV, Nenajdenkob VG, Muzalevskiy VM, Mahmudov KT, Kopylovich MN. Zinc(II)-1,3,5-triazapentadienate complex as effective catalyst in Henry reaction. Catal Today. 2013;217:76–9.

    Article  Google Scholar 

  34. Huber PC, Reis GP, Amstalden MCK, Lancellotti M, Almeida WP. Synthesis, spectroscopic characterizations and antimicrobial activity of copper and zinc complexes of levofloxacin, ciprofloxacin and 3-carboxy-4-quinolone. Polyhedron. 2013;57:14–9.

    Article  CAS  Google Scholar 

  35. Khalaji AD, Grivani G, Seyyedi M, Fejfarova K, Dusek M. Zinc(II) and mercury(II) complexes [Zn((2,6–Cl–ba)2en)I2] and [Hg((2,6–Cl–ba)2en)Br 2] with the bidentate Schiff base ligand (2,6–Cl–ba)2en: synthesis, characterization and crystal structures. Polyhedron. 2013;49:19–23.

    Article  CAS  Google Scholar 

  36. Cimerman Z, Galic N, Bosnerb B. The Schiff bases of salicylaldehyde and aminopyridines as highly sensitive analytical reagents. Analytica Chim Acta. 1997;343:145–53.

    Article  CAS  Google Scholar 

  37. Haggag SMS, Farag AAM, Abdel Refea M. Successive ion layer adsorption and reaction (SILAR) technique synthesis of Al(III)–8-hydroxy-5-nitrosoquinolate nano-sized thin films: characterization and factors optimization. Spectrochim Acta Part A. 2013;102:150–8.

    Article  CAS  Google Scholar 

  38. Haggag SMS, Farag AAM, Abdel M. Refea. Synthesis, characterization and optical-electrical properties of nano Al(III)-8-hydroxy-5,7-dinitroquinolate thin films. Thin Solid Films. 2014;566:38–44.

    Article  CAS  Google Scholar 

  39. Buchold DHM, Feldmann C. Microemulsion approach to non-agglomerated and crystalline nanomaterials. Adv Funct Mater. 2008;18:1002–11.

    Article  CAS  Google Scholar 

  40. Garg BS, Nandan Kumar D. Spectral studies of complexes of nickel(II) with tetradentate schiff bases having N2O2 donor groups. Spectrochim Acta, Part A. 2003;59:229–34.

    Article  CAS  Google Scholar 

  41. Anthony samy A, Balasubramanian S. Synthesis, spectral, thermal and electrochemical studies of nickel (II) complexes with N2O2 donor ligands. Inorg Chem Commun. 2005;8:908–11.

    Article  CAS  Google Scholar 

  42. Soliman MH, Mohamed GG. Preparation, spectroscopic and thermal characterization of new metal complexes of verlipride drug. Spectrochim Acta Part A. 2012;91:11–7.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Alexandria University, Ibrahimia, P.O. Box 426, Alexandria, 21321, Egypt

    Sawsan M. S. Haggag & Ibrahim A. M. Abdel-Hamid

Authors
  1. Sawsan M. S. Haggag
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ibrahim A. M. Abdel-Hamid
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sawsan M. S. Haggag.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Haggag, S.M.S., Abdel-Hamid, I.A.M. A tridentate (O, N, O) donor Schiff base zinc(II) nano complex. J Therm Anal Calorim 119, 737–746 (2015). https://doi.org/10.1007/s10973-014-4200-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-014-4200-x

Keywords

Search

Navigation