Abstract
In this paper, sol–gel-based transparent easy-to-clean (ETC) coatings are fabricated using organic–inorganic hybrid precursors and fluorinated silane-based hydrophobic surfactants. ETC coatings were applied on different plastic materials such as polycarbonate, poly(methyl methacrylate) and polyethylene terephthalate. Due to the low temperature resistance of the plastic materials, usually lower than 120 °C, low temperature processes such as ammonia gas curing and ultraviolet irradiation curing were employed for coatings development. Alumina nanoparticles were used to improve the mechanical properties of the coatings, and antimicrobial effect was realized by incorporation of silver nanoparticles, and high bacterial killing rates were obtained with very low silver concentration (50 ppm). All the coatings developed on different substrates show high water/hexadecane contact angles with good wet scrubbing resistance.
Graphical Abstract
Abrasion-resistant multifunctional sol–gel coating on PMMA substrate
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References
Nosonovsky M, Bhushan B (2008) J Phys: Condens Matter 20:225009
Nosonovsky M, Bhushan B (2009) Curr Opin Colloid Interface Sci 14:270
Tuteja A, Choi W, Ma M, Mabry JM, Mazzella SA, Rutledge GC (2008) Science 318:1618
Genzer J, Efimenko K (2006) Biofouling 22:339
Ma M, Hill RM (2006) Curr Opin Colloid Interface Sci 1:193
Jung YC, Bhushan B (2006) Nanotechnology 17:4970
Hsieh CT, Wu FL, Yang SY (2008) Surf Coat Technol 202:6103
Ressine A, Marko-Varga G, Laurell T (2007) Biotechnol Annu Rev 13:149
Hur JI, Meng DD, Kim CJ (2010) In: Proc. IEEE Int. Conf. Micro Electro mechanical systems, Hong Kong, China
Aegerter MA, Almeida R, Soutar A, Tadanaka K, Yang H (2008) J Sol-Gel Sci Technol 47:203
Akamatsu Y, Mikita K, Inaba H, Minami H (2001) Thin Solid Films 389:138
Kamitani K, Teranishi T (2003) J Sol-Gel Sci Technol 26:823
Huang SI, Shen YJ, Chen H (2009) Appl Surf Sci 255:7040
Wright JD, Sommerdijk NAJM (2000) Sol-gel materials: chemistry and applications. Taylor & Francis, London
Jeong HJ, Kim DK, Lee SB, Kwon SH, Kadonoz K (2001) J Colloid Interface Sci 235:130
Kulinich SA, Farzaneh M (2004) Surf Sci 573:379
Philippe FB, Herve GF (1994) SPIE Sol-Gel Optics III Proc 2288:25
Wu G, Wang J, Shen J, Yang T (2000) J Non Cryst Solids 275:169
Meredith P, Harvey M (2010) Silica and silica-like films and method of production, US Patent No. 7642199B2
Guo L, Yuan W, Lu Z, Li CM (2013) Colloid Surf A Physicochem Eng Asp 439:69
Vasilev K, Cook J, Griesser HJ (2009) Expert Rev Med Devices 6:553
Zhang X, Qian M, Liu YC, Xie H (2010) Key Eng Mater 447–448:740
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This work is partially financial supported by Singapore SPRING TIP funding for SMEs.
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Zhang, X., Cai, R., Wang, J.Y. et al. Easy-to-clean multifunctional coatings by sol–gel processing for polymer substrates. J Sol-Gel Sci Technol 75, 17–24 (2015). https://doi.org/10.1007/s10971-015-3669-5
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DOI: https://doi.org/10.1007/s10971-015-3669-5