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Fabrication and properties of KMnO4-treated functionalized biaxially oriented polypropylene (BOPP) films coated with a hybrid material

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Abstract

KMnO4-treated functionalized biaxially oriented polypropylene (BOPP) films coated with a hybrid material were synthesized, and the abrasion resistance properties of the resultant films were examined. The presence of functional groups was confirmed using Fourier-transform infrared spectroscopy, transmittance measurements were performed using an ultraviolet–visible spectrophotometer, and the intensities of the films were measured using a universal testing machine. The abrasion resistance and roughness of the composite films were significantly affected by modification of the BOPP film. The transmittance of the modified films obviously improved with the addition of Al2O3 sol, and the mechanical properties of the treated films were improved by the coatings. The abrasion resistance of one of the functionalized films (sample S159) increased by 79.5 % compared with that of the original film.

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References

  1. Lin Y, Hiltner A, Baer E (2010) A new method for achieving nanoscale reinforcement of biaxially oriented polypropylene film. Polymer 51:4218–4224

    Article  Google Scholar 

  2. Kalapat N, Amornsakchai T (2012) Surface modification of biaxially oriented polypropylene (BOPP) film using acrylic acid-corona treatment: part I. Properties and characterization of treated film. Surf Coat Technol 27:594–601

    Article  Google Scholar 

  3. Pandiyaraj K-N, Selvarajan V, Deshmukh R–R, Gao C (2009) Modification of surface properties of polypropylene (PP) film using DC glow discharge air plasma. Appl Surf Sci 255:3965–3971

    Article  Google Scholar 

  4. Tamura S, Kuramoto I, Kanai T (2012) The effect of molecular structure of polypropylene on stretchability for biaxially oriented film. Polym Eng Sci 52:1383–1393

    Article  Google Scholar 

  5. Dasari A, Rohrmann J, Misra R-D-K (2002) Micro-and nanoscale evaluation of scratch damage in poly (propylene)s. Macromol Mater Eng 287:889–903

    Article  Google Scholar 

  6. Xiang C, Sue HJ, Chu J, Coleman B (2001) Scratch behavior and material property relationship in polymers. J Polym Sci, Part B: Polym Phys 39:47–59

    Article  Google Scholar 

  7. Xie J, Xin D, Cao H, Wang C, Zhao Y, Yao L, Ji F, Qiu Y (2011) Improving carbon fiber adhesion to polyimide with atmospheric pressure plasma treatment. Surf Coat Technol 206:191–201

    Article  Google Scholar 

  8. Vesel A, Mozetic M (2012) Surface modification and ageing of PMMA polymer by oxygen plasma treatment. Vacuum 86:634–637

    Article  Google Scholar 

  9. Hite D-A, Colombe Y, Wilson A-C, Brown K-R, Warring U, Jordens R, Jost J-D, Mckay K-S, Pappas D-P, Leibfred D, Wineland D-J (2012) 100-fold reduction of electric-field noise in an ion trap cleaned with in situ argon-ion-beam bombardment. Phys Rev Lett 109:103001

    Article  Google Scholar 

  10. Bian X, Chen L, Yu D, Wang L, Guan Z (2012) Impact of surface roughness on corona discharge for 30-year operating conductors in 500-kV ac power transmission line. IEEE Trans Power Deliver 27:1693–1695

    Article  Google Scholar 

  11. Kyomoto M, Moro T, Takatori Y, Kawaguchi H, Nakamura K, Ishihara K (2010) Self-initiated surface grafting with poly (2-methacryloyloxyethyl phosphorylcholine) on poly (ether–ether-ketone). Biomaterials 31:1017–1024

    Article  Google Scholar 

  12. Li J, Wang M, Shen Y (2012) Chemical modification on top of nanotopography to enhance surface properties of PDMS. Surf Coat Technol 206:2161–2167

    Article  Google Scholar 

  13. Ji W-G, Hu J-M, Liu L, Zhang J, Cao C (2007) Improving the corrosion performance of epoxy coatings by chemical modification with silane monomers. Surf Coat Technol 201:4789–4795

    Article  Google Scholar 

  14. Fávaro S-L, Rubira A-F, Muniz E-C, Radovanovic E (2007) Surface modification of HDPE, PP, and PET films with KMnO4/HCl solutions. Polym Degrad Stab 92:1219–1226

    Article  Google Scholar 

  15. Jeon S-J, Lee J–J, Kim W, Chang T, Koo S (2008) Hard coating films based on organosilane-modified boehmite nanoparticles under UV/thermal dual curing. Thin Solid Films 516:3904–3909

    Article  Google Scholar 

  16. Wan Y, Sun B, Liu W, Qi C (2012) Tribological performance of fatty acid modification of sol–gel TiO2 coating. J Sol Gel Sci Technol 61:558–564

    Article  Google Scholar 

  17. Lionti K, Toury B, Boissière C, Benayoun S, Miele P (2013) Hybrid silica coatings on polycarbonate: enhanced properties. J Sol Gel Sci Technol 65:1–9

    Article  Google Scholar 

  18. Xu L, Fu Y, Du M (2011) Investigation on structures and properties of shape memory polyurethane/silica nanocomposites. Chin J Chem 29:703–710

    Article  Google Scholar 

  19. Wang J, Zhu Y, Fu Y (2013) Abrasion resistance of biaxially oriented polypropylene films coated with nanocomposite hard coatings. Appl Surf Sci 285P:697–701

    Article  Google Scholar 

  20. Xu T, Zhao J, Xu K, Xu Q (1997) Study on the tribological properties of ultradispersed diamond containing soot as an oil additive©. Tribol Trans 40:178–182

    Article  Google Scholar 

  21. Lakshmi R-V, Bharathidasan T, Basu B-J (2011) Superhydrophobic sol–gel nanocomposite coatings with enhanced hardness. Appl Surf Sci 257:10421–10426

    Article  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the Instrumental Analysis Center of Zhejiang Sci-Tech University for allowing the use of their characterization facilities. We also thank the technicians for their assistance in the analyses and for the technical discussions.

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Correspondence to Yaqin Fu.

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Wang, J., Zhu, Y. & Fu, Y. Fabrication and properties of KMnO4-treated functionalized biaxially oriented polypropylene (BOPP) films coated with a hybrid material. J Sol-Gel Sci Technol 71, 176–183 (2014). https://doi.org/10.1007/s10971-014-3352-2

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  • DOI: https://doi.org/10.1007/s10971-014-3352-2

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