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Strong emitting sol–gel materials based on interaction of luminescence dyes and lanthanide complexes with silver nanoparticles

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Abstract

We show here how luminescence of fluorescent dyes and lanthanide complexes in sol–gel matrix can be intensified as a result of interaction of the species with silver nanoparticles. Preparation of silver nanoparticles in sol–gel composite precursor is outlined and their structural characterization are presented. Zirconia-glymo and Glymo-polyurethane-silica were used as host matrices for silver nanoparticles and the fluorescence species. The intensification of fluorescence was demonstrated by steady state spectroscopy.

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References

  1. Barnes WL, Dereux A, Ebbesen TW (2003) Surface plasmon subwavelength optics. Nature 424:824. doi:10.1038/nature01937

    Article  PubMed  ADS  CAS  Google Scholar 

  2. Willets KA, Van Duyne RP (2007) Localized surface plasmon resonance spectroscopy and sensing. Annu Rev Phys Chem 58:267–297. doi:10.1146/annurev.physchem.58.032806.104607

    Google Scholar 

  3. Margueritat J, Gonzalo J, Afonso CN, Bachelier B, Mlayah A, Laarakker AS, Murray DB, Saviot L (2007) From silver nanolentils to nanocolumns: surface plasmon–polaritons, confined acoustic vibrations. Appl Phys A 89:369–372

    Article  ADS  CAS  Google Scholar 

  4. Hilgera A, Cuppers N, Tenfelde M, Kreibig U (2000) Surface and interface effects in the optical properties of silver nanoparticles. Eur Phys J D 10:115–118. doi:10.1007/s100530050531

    Article  ADS  Google Scholar 

  5. Reisfeld R, Eyal M, Brusilovsky D (1988) Absorption spectra, energy dispersive analysis of X-rays, transmission electron microscopy of silver particles in sol-gel glass films. Chem Phys Lett 153:210–214. doi:10.1016/0009-2614(88)85214-X

    Article  ADS  CAS  Google Scholar 

  6. Reisfeld R, Weiss A, Saraidarov T, Yariv E, Ishchenko A (2004) Solid state lasers based on inorganic-organic hybrid materials obtained by sol-gel polymer technology. Polym Adv Technol 15:291–301

    Article  CAS  Google Scholar 

  7. Reisfeld R, Saraidarov T, Pietraszkiewicz M, Lis S (2001) Luminescent europium(III) compounds in zirconia xerogels. Chem Phys Lett 349:266. doi:10.1016/S0009-2614(01)01215-5

    Article  ADS  CAS  Google Scholar 

  8. Philipp G, Schmidt H (1986) The reactivity of TiO2 and ZrO2 in organically modified silicates. J Non-Cryst Solids 82:31–36. doi:10.1016/0022-3093(86)90107-9

    Article  ADS  CAS  Google Scholar 

  9. Reisfeld R, Pietraszkiewicz M, Saraidarov T, Levchenko V (2008) J Rare Earths REMAT 08 (accepted)

  10. Lakowicz JR (2006) Plasmonics in biology and plasmon-controlled fluorescence. Plasmonics 1:5–33. doi:10.1007/s11468-005-9002-3

  11. Lakowicz JosephR, Krishanu Ray, Mustafa Chowdhury, Henryk Szmacinski, Yi Fu, Jian Zhang, Kazimierz Nowaczyk (2008) Plasmon-controlled fluorescence: a new paradigm in fluorescence spectroscopy. R Soc Chem Anal 133:1308–1346. doi:10.1039/b802918k

    Article  CAS  Google Scholar 

  12. Meng W, Lakowicz JR, Geddes CD (2005) J Fluoresc 15(1):53–59

    Google Scholar 

  13. Malashkevich GE, Shevchenko GP, Serezhkina SV, Pershukevich PP, Semkova GI, Glushonok GK (2007) Effect of the Chemical State of Silver on the Luminescence Properties of GeO2–Eu2O3–Ag Films. Phys Solid State 49(10):1891–1902. doi:10.1134/S1063783407100137

    Article  ADS  CAS  Google Scholar 

  14. Reisfeld R (2003) Rare Earth Ions:Their Spectroscopy of Cryptates and Related Complexes in Glasses in. Struct Bond 106:209–235

    Google Scholar 

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Acknowledgements

We are greatly thankful to Prof. J. Lakowicz for providing his resent review and to Prof. Oscar Malta for helpful discussion clarifying very important points.

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Correspondence to R. Reisfeld.

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Reisfeld, R., Saraidarov, T. & Levchenko, V. Strong emitting sol–gel materials based on interaction of luminescence dyes and lanthanide complexes with silver nanoparticles. J Sol-Gel Sci Technol 50, 194–200 (2009). https://doi.org/10.1007/s10971-009-1892-7

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  • DOI: https://doi.org/10.1007/s10971-009-1892-7

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