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Synthesis and characterization of mesoporous silica green catalyst, functionalized with nicotinic acid and its use for synthesis of pyran heterocyclic compounds

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Abstract

A simple and convenient method has been used to prepare an SBA-Nicotinic acid (SBA-Niacin) composite on SBA-15 mesoporous silica as support. The composite was easily prepared by nucleophilic substitution of SBA-propylchloride with nicotinic acid. The structural properties of SBA-Niacin were systematically investigated by Fourier transform infrared spectroscopy, scanning electron microscopy, transmission and scanning electron microscopy, X-ray diffraction spectroscopy, thermal gravimetric analysis and Brunauer Emmett Teller. The catalytic activity of this nanocomposite was successfully tested through the one-pot synthesis of pyran annulated heterocyclic compounds via three-component couplings of aromatic aldehydes, malononitrile and β-diketone (dimedone and 4-hydroxy-6-methyl-2-pyrone) under solvent-free conditions.

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Acknowledgements

We gratefully acknowledge the support of this work by Abadan branch of Islamic Azad University.

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Authors and Affiliations

  1. Chemistry Department, Production Technology Research Institute- ACECR, Ahvaz, Iran

    Jamal Davarpanah

  2. Department of Chemical Engineering, Abadan Branch, Islamic Azad University, Abadan, Iran

    Somayeh Elahi & Parizad Rezaee

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  1. Jamal Davarpanah
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  2. Somayeh Elahi
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  3. Parizad Rezaee
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Correspondence to Somayeh Elahi.

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Davarpanah, J., Elahi, S. & Rezaee, P. Synthesis and characterization of mesoporous silica green catalyst, functionalized with nicotinic acid and its use for synthesis of pyran heterocyclic compounds. J Porous Mater 25, 161–170 (2018). https://doi.org/10.1007/s10934-017-0429-7

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