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Synthesis and characterization of a new anionic zinc-adeninate metal–organic framework, [Zn3(ad)(BTC)2·(Me2NH2), 5.75 DMF, 0.25 H2O]

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Abstract

A new anionic zinc-adeninate metal–organic framework, [Zn3(ad)(BTC)2·(Me2NH2), 5.75DMF, 0.25H2O] (ad = adeninate; BTC = benzene tricarboxylate; DMF = dimethylformamide), was synthesized via solvothermal reaction at 403 K for 24 h between adenine, zinc acetate dehydrate, and benzene tricarboxylic acid in DMF. The single-crystal structure of the framework was determined by single-crystal X-ray diffraction techniques in the monoclinic space group P2(1)/n and was refined to the final error indices R 1/wR 2 = 0.0663/0.1714 for I > 2sigma(I). The coordination of adenine and BTC expands the structure in different directions, resulting in a three dimensional structure. This framework contains a pore with the size ca. 6.6 × 3.9 Å. The chemical stability, thermal stability, and cation-exchange characteristics were investigated by powder XRD, TGA, EDX, 1H NMR, and EA.

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Acknowledgments

This work is supported by Aspiring Researcher Program through Seoul National University (SNU) in 2013. This work was also performed in collaboration with Prof. Nathaniel L. Rosi from the University of Pittsburgh.

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Authors and Affiliations

  1. Department of Chemistry Education, Seoul National University, Seoul, 151-748, Republic of Korea

    Jihyun An

  2. Department of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, PA, 15260, USA

    Steven J. Geib

  3. Department of Chemistry, Chung-Ang University, Seoul, 156-756, Republic of Korea

    Myung-Gil Kim

  4. Department of Applied Chemistry, Andong National University, Andong, 760-749, Republic of Korea

    Sik Young Choi & Woo Taik Lim

Authors
  1. Jihyun An
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  2. Steven J. Geib
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  3. Myung-Gil Kim
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  4. Sik Young Choi
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  5. Woo Taik Lim
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Correspondence to Jihyun An or Woo Taik Lim.

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An, J., Geib, S.J., Kim, MG. et al. Synthesis and characterization of a new anionic zinc-adeninate metal–organic framework, [Zn3(ad)(BTC)2·(Me2NH2), 5.75 DMF, 0.25 H2O]. J Porous Mater 22, 867–875 (2015). https://doi.org/10.1007/s10934-015-9960-6

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