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Tuning the crystal size and morphology of the substituted imidazole material, SIM-1

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Abstract

Zeolitic imidazolate frameworks (ZIFs) are attractive materials for liquid and gas separations. They are chemically and thermally stable and their pores sizes/pore windows can be modified for enhanced performance. Substituted imidazolate material-1 (SIM-1) is a ZIF that crystallizes in the SOD and RHO topologies. Herein, we report a variety of new syntheses for SIM-1 in the SOD and RHO topologies using solvothermal in situ and ex situ reaction methods including microwave synthesis and linker exchange that result in nanoparticles with a narrow size distribution.

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Acknowledgments

We would like to thank the Robert A. Welch Foundation AT1153 for supporting this work.

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Authors and Affiliations

  1. Department of Chemistry, University of Texas at Dallas, 800 West Campbell Road, Richardson, TX, 75080, USA

    Anne M. Marti, Mylinh Van & Kenneth J. Balkus Jr.

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  1. Anne M. Marti
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  2. Mylinh Van
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  3. Kenneth J. Balkus Jr.
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Correspondence to Kenneth J. Balkus Jr..

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Marti, A.M., Van, M. & Balkus, K.J. Tuning the crystal size and morphology of the substituted imidazole material, SIM-1. J Porous Mater 21, 889–902 (2014). https://doi.org/10.1007/s10934-014-9840-5

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