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Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials

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Abstract

The presented report focuses on the testing of heterogenized methyltrioxorhenium (MTO) in indene epoxidation. A range of mesoporous materials with different SiO2/Al2O3 ratios, namely aluminosilicates type Siral and MCM-41 silica and fumed silica, were used as supports for immobilization of MTO. The tested support materials and prepared catalytic systems exhibited high surface area, well-defined regular structure and narrow pore size distribution of mesopores and therefore represent good quality catalysts for various reactions. The immobilized MTO on various supports was tested for the preparation of 1,2-epoxyindane using two forms of hydrogen peroxide as oxidation agents, namely aqueous solution of hydrogen peroxide and its anhydrous form, urea-hydrogen peroxide. The prepared catalysts were successfully used for the preparation of 1,2-epoxyindane with achieved 100 % selectivities to the desired product at high conversions of indene.

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Acknowledgments

The publication was supported by the UniCRE project, funded by the EU Structural Funds and the state budget of the Czech Republic. M. Lhotka is acknowledged for performing nitrogen adsorption measurements. We thank Sasol Germany GmbH for the supply of Siral samples.

Conflict of interest

The authors declare that they have no conflict of interest.

Ethical standard

The authors declare that the experiments comply with the current laws of Czech Republic.

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Authors and Affiliations

  1. Institute of Chemical Technology Prague, Technicka 5, 166 28, Prague 6, Czech Republic

    Martina Stekrova, Hana Minarikova, Eliska Vyskocilova & Libor Cerveny

  2. Research Institute of Inorganic Chemistry, Inc., Revolucni 1524, 400 01, Usti nad Labem, Czech Republic

    Martina Stekrova & Jiri Kolena

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  1. Martina Stekrova
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  2. Hana Minarikova
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  3. Eliska Vyskocilova
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  4. Jiri Kolena
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  5. Libor Cerveny
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Correspondence to Martina Stekrova.

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Stekrova, M., Minarikova, H., Vyskocilova, E. et al. Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials. J Porous Mater 21, 757–767 (2014). https://doi.org/10.1007/s10934-014-9822-7

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  • DOI: https://doi.org/10.1007/s10934-014-9822-7

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