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Supramolecular approach to metal–organic gels using excess organic ligand as building units

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Abstract

A metal–organic gels containing Ag(4,4′-bipyridine)NO3 metal–organic framework and 4,4′-bipyridine units were hydrothermally synthesized using excess 4,4′-bipyridine ligand as building units. The metal–organic gels structure was characterized by various spectroscopic methods and a mechanism of assembly was discussed on the basis of the obtained data. The metal–organic gels retained the characteristics of both the metal–organic framework and gels; furthermore, the reversible hydration/dehydration, reversible anion exchange, and responsive properties were also investigated.

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Acknowledgments

We gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (Grant Nos. 21171133 and 21271143).

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Authors and Affiliations

  1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, People’s Republic of China

    Huayi Zhao, Qian Shi, Hongping Xiao & Xinhua Li

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  1. Huayi Zhao
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  2. Qian Shi
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  3. Hongping Xiao
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  4. Xinhua Li
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Correspondence to Xinhua Li.

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Zhao, H., Shi, Q., Xiao, H. et al. Supramolecular approach to metal–organic gels using excess organic ligand as building units. J Porous Mater 21, 691–697 (2014). https://doi.org/10.1007/s10934-014-9816-5

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  • DOI: https://doi.org/10.1007/s10934-014-9816-5

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