Skip to main content
Log in

Temperature-time duality exemplified by Ising magnets and quantum-chemical many electron theory

  • Original Paper
  • Published:
Journal of Mathematical Chemistry Aims and scope Submit manuscript

Abstract

In this work, we first present a detailed analysis of temperature-time duality in the 3D Ising model, by inspecting the resemblance between the density operator in quantum statistical mechanics and the evolution operator in quantum field theory, with the mapping β = (k B T)−1 → it. We point out that in systems like the 3D Ising model, for the nontrivial topological contributions, the time necessary for the time averaging must be infinite, being comparable with or even much larger than the time of measurement of the physical quantity of interest. The time averaging is equivalent to the temperature averaging. The phase transitions in the parametric plane (β, it) are discussed, and a singularity (a second-order phase transition) is found to occur at the critical time t c , corresponding to the critical point β c (i.e, T c ). It is necessary to use the 4-fold integral form for the partition function for the 3D Ising model. The time is needed to construct the (3 + 1)D framework for the quaternionic sequence of Jordan algebras, in order to employ the Jordan-von Neumann-Wigner procedure. We then turn to discuss quite briefly temperature-time duality in quantum-chemical many-electron theory. We find that one can use the known one-dimensional differential equation for the Slater sum S(x, β) to write a corresponding form for the diagonal element of the Feynman propagator, again with the mapping β → it.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Zhang Z.D.: Phil. Mag. 87, 5309 (2007)

    Article  CAS  Google Scholar 

  2. Ławrynowicz J., Marchiafava S., Niemczynowicz A.: Adv. Appl. Clifford Algebra 20, 733 (2010)

    Article  Google Scholar 

  3. J. Ławrynowicz, S. Marchiafava, M. Nowak-Kȩpczyk, Trends Differential Geometry, Complex Analysis and Mathemtical Physics, in Proceedings of the 9th International Workshop on Complex Structures, Integrability and Vector Fields, Sofia, Bulgaria, 25–29 August 2008, ed. by K. Sekigawa, V.S. Gerdjikov, S. Dimiev (World Scientific, Singapore), pp. 156–166 doi:10.1142/9789814277723_0018

  4. Lawrynowicz J.: Act. Phys. Superf. 11, 101 (2009)

    Google Scholar 

  5. March N.H.: Electron Density Theory of Atoms and Molecules. Academic, New York (1992)

    Google Scholar 

  6. Parr R.G., Yang W.: Density Functional Theory of Atoms and Molecules. Oxford University Press, New York (1989)

    Google Scholar 

  7. March N.H., Howard I.A.: Phys. Status Solidi B. 237, 265 (2003)

    Article  CAS  Google Scholar 

  8. Zhang Z.D.: Philosphy Mag. 88, 3097 (2008)

    Article  CAS  Google Scholar 

  9. Das A.: Field Theory, a Path Integral Approach. World Scientific, Singapore (1993)

    Book  Google Scholar 

  10. Francesco P.D., Mathieu P., Sénéchal D.: Conformal Field Theory. Springer, New York (1996)

    Google Scholar 

  11. Binney J.J., Dowrick N.J., Fisher A.J., Newman M.E.J.: The Theory of Critical Phenomena, An Introduction to the Renormalization Group. Clarendon Press, Oxford (1992)

    Google Scholar 

  12. Jordan P., von Neumann J., Wigner E.: On an algebraic generalization of the quantum mechanical formalism. Ann. Math. 35, 29–64 (1934)

    Article  Google Scholar 

  13. Zhang Z.D., March N.H.: Phase Trans. 84, 299 (2011)

    Article  CAS  Google Scholar 

  14. Z.D. Zhang, Phil. Mag. 89, 765 (2009). See also 0812.0194v6 for more detailed discussions, specially, these on singularities at/near infinite temperature.

  15. Jones W., March N.H.: Theoretical Solid–State Physics. Dover, New York (1985)

    Google Scholar 

  16. Howard I.A., March N.H., Nieto L.M.: Phys. Rev. A 66, 054501 (2002)

    Article  Google Scholar 

  17. De Marco B., Jin D.S.: Science 285, 1703 (1999)

    Article  CAS  Google Scholar 

  18. Sondheimer E.H., Wilson A.H.: Proc. R. Soc. Lond. Ser. A 210, 173 (1951)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Z. D. Zhang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, Z.D., March, N.H. Temperature-time duality exemplified by Ising magnets and quantum-chemical many electron theory. J Math Chem 49, 1283–1290 (2011). https://doi.org/10.1007/s10910-011-9820-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10910-011-9820-9

Keywords

Navigation