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Experimental Measurement of Carbon Dioxide Polarizability in the Solid State

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Abstract

We have experimentally determined the polarizability of \(\hbox {CO}_{2}\) using the Lorentz–Lorenz equation by simultaneously measuring the density and the refractive index. The \(\hbox {CO}_{2}\) conditions were solid phase, \(10^{-7}\) mbar pressure, and temperature range 10–86 K. The polarizability value compares well with previous gas-phase experimental results and the results from simulations, and does not depend on the temperature of \(\hbox {CO}_{2}\) ice formation. This value is constant in the temperature range studied, despite a structural change from amorphous to crystalline.

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Acknowledgments

This work was supported by the Spanish Ministerio de Economía y Competitividad (FIS2013-48087-C2-2-P).

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Authors and Affiliations

  1. Centro de Tecnologías Físicas, Universitat Politècnica de València, 46022, Valencia, Spain

    M. Domingo, R. Luna, M. A. Satorre, C. Santonja & C. Millán

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  1. M. Domingo
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  2. R. Luna
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  3. M. A. Satorre
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  4. C. Santonja
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  5. C. Millán
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Correspondence to M. Domingo.

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Domingo, M., Luna, R., Satorre, M.A. et al. Experimental Measurement of Carbon Dioxide Polarizability in the Solid State. J Low Temp Phys 181, 1–9 (2015). https://doi.org/10.1007/s10909-015-1326-6

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  • DOI: https://doi.org/10.1007/s10909-015-1326-6

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