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Syntheses, Structures and Catalytic Properties of Cobalt(II) and Silver(I) Coordination Polymers Based on Flexible Bis(2-methyl benzimidazole) and Dicarboxylic Acids

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Abstract

Two coordination polymers formulated as [Co2(2,6-ndc)2(L)] n (1) and [Ag(L)(1,4-Hndc)] n (2) (L = 1,1′-(1,4-butanediyl)bis(2-methylbenzimidazole), 2,6-H2ndc = 2,6-naphthalenedicarboxylic acid, 1,4-H2ndc = 1,4-naphthalenedicarboxylic acid) were synthesized under hydrothermal conditions and characterized by IR, elemental analysis, and single-crystal X-ray diffraction. The structural analysis reveals that complex 1 exhibits an unprecedented 3D framework with threefold interpenetrating xah topology. Complex 2 shows a 1D “Ω”-like chains bridged by L ligands, which is further extended via O–H···O hydrogen bonding interactions into a 2D (4,4) supramolecular layer. The thermal stability and catalytic properties of two complexes for the degradation of Congo red dye in a Fenton-like process was also investigated.

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Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation – Steel and Iron Foundation of Hebei Province (B2015209299), the Graduate Student Innovation Fund of North China University of Science and Technology (2015S13).

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Authors and Affiliations

  1. College of Chemical Engineering, North China University of Science and Technology, Tangshan, 063009, Hebei, People’s Republic of China

    Xu Zhang, Gui-Ying Dong, Yong-Guang Liu & Guang Hua Cui

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  1. Xu Zhang
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  2. Gui-Ying Dong
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  3. Yong-Guang Liu
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  4. Guang Hua Cui
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Correspondence to Gui-Ying Dong or Guang Hua Cui.

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Zhang, X., Dong, GY., Liu, YG. et al. Syntheses, Structures and Catalytic Properties of Cobalt(II) and Silver(I) Coordination Polymers Based on Flexible Bis(2-methyl benzimidazole) and Dicarboxylic Acids. J Inorg Organomet Polym 26, 62–68 (2016). https://doi.org/10.1007/s10904-015-0281-7

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  • DOI: https://doi.org/10.1007/s10904-015-0281-7

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