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A Cationic Two-Dimensional Zn(II) Coordination Polymer, Crystal Structure and Fluorescence Emission

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Abstract

The reaction of 1,4-bis((2H-benzo[d]imidazol-2-yl)methyl) naphthalene and pyridinium 1,1,2,3,3-pentacyanopropenide (PCP) with Zn(II) salts yielded two-dimensional (2D) chain coordination polymer ([Zn (C26H20N4) 2+2 ][C8N5 −]2). The 2D structure was synthesized via solvothermal synthesis; and structurally characterized by elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffraction. The X-ray single crystal revealed that [Zn(C26H20N4) 2+2 ][C8N5 –]2 is comprised of the [Zn(C26H20N4) 2+2 ] cationic chains and PCP anion [C8N5 –]2. As a result of the porous nature of the cationic 2D network, the PCP-anions are located at the rhombic windows that balance the charge of 2D structure. The luminescent and thermal properties were also investigated. The fluorescence emission of the coordination polymer was investigated in the presence of hydrocarbon molecules such as (anthracene, toluene, and benzene).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Port Said University, 23 December St., Port Said, 42521, Egypt

    Samir Alghool

  2. Department of Chemistry, Faculty of Science, Taif University, Taif, 5700, Kingdom of Saudi Arabia

    Samir Alghool

  3. Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA, 24061, USA

    Carla Slebodnick

Authors
  1. Samir Alghool
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  2. Carla Slebodnick
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Correspondence to Samir Alghool.

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Alghool, S., Slebodnick, C. A Cationic Two-Dimensional Zn(II) Coordination Polymer, Crystal Structure and Fluorescence Emission. J Inorg Organomet Polym 25, 1386–1393 (2015). https://doi.org/10.1007/s10904-015-0251-0

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