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Ferrocenyldithiophosphonate Containing Conducting Polymers and Theirs Electrochromic Application

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Abstract

In this study, a new ferrocenyldithiophosphonate functionalized; [O-1-(4-phenyl)-1H-pyrrole ferrocenyldithiophosphonate (TPFc)] monomer and its conductive copolymers with pyrrole and 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)butane-1-amine were synthesized, characterized and their electrochromic properties were investigated. The spectroelectrochemical analyses demonstrated that the copolymer films reveal a reversible cycling with distinctive color changes in their reduced/oxidized forms. For the copolymer films P(TPFc-co-Py)/DCM, P(TPFc-co-Py)/CH3CN and P(TPFc-co-TPA)/DCM, the maximum optical contrasts (ΔT %) were measured as 28, 12 and 27 % at 800, 900 and 900 nm, respectively. Spectroelectrochemical analysis also revealed that all copolymers prepared with TPFc have lower band gaps compared to those of corresponding polymers.

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Acknowledgments

This work was supported by Scientific and Technological Research Council of Turkey (TUBITAK; Project number: 111T074) and PAUBAP (2011FBE74).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Art, Pamukkale University, Denizli, Turkey

    Tugba Soganci, Metin Ak, Seyda Ocal & Mehmet Karakus

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  1. Tugba Soganci
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  2. Metin Ak
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  3. Seyda Ocal
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  4. Mehmet Karakus
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Correspondence to Metin Ak.

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Soganci, T., Ak, M., Ocal, S. et al. Ferrocenyldithiophosphonate Containing Conducting Polymers and Theirs Electrochromic Application. J Inorg Organomet Polym 25, 1011–1018 (2015). https://doi.org/10.1007/s10904-015-0202-9

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  • DOI: https://doi.org/10.1007/s10904-015-0202-9

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