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Effect of B2O3 on Structure and Properties of CaO–MgO–B2O3–Al2O3–SiO2 Glasses

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Abstract

xB2O3-(1 − x) (60SiO2–15Al2O3–15MgO–10CaO) glasses with various x around 5–30 mol% at the step of 5 mol% are prepared by the melting-quenching method at 1,450 °C for 3 h. The IR data indicate that replacing other components by B2O3 levels up the amount of [BO4] tetrahedron and boron-oxygen rings, forcing [AlO4] tetrahedron to drop gradually. The glass transition temperature (Tg), crystallization temperature (Tc) and thermal stability (∆T) rise when B2O3 is present in lower concentrations (≤20 mol%); accordingly the glass network enhances. However, further increase in concentration of B2O3 (>20 mol%) reduces the Tg, Tc and ∆T. We utilize temperature-gradient furnace to measure the G6 glass, while the re-melt sample and crystallized phase are observed from polarizing microscope destroying microstructure. As B2O3 content move up, falls in dielectric constant (εr) and loss (tanδ) can be associated with drop of cations polarizability as well as concentration, along with glass network rigidity ascending.

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Acknowledgments

This work is supported by Natural Science Foundation of Shandong Province (Nos. ZR2012EMM019), Natural Science Foundation of Shandong Province (Nos. ZR2011EMQ005) and Natural Science Foundation (Nos. 51172093, 51042009).

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Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, School of Materials Science and Engineering, University of Jinan, Jinan, 250022, China

    Sanxi Huang, Sheng Li, Fengnian Wu & Yunlong Yue

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  1. Sanxi Huang
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  2. Sheng Li
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  3. Fengnian Wu
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  4. Yunlong Yue
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Correspondence to Yunlong Yue.

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Huang, S., Li, S., Wu, F. et al. Effect of B2O3 on Structure and Properties of CaO–MgO–B2O3–Al2O3–SiO2 Glasses. J Inorg Organomet Polym 25, 816–822 (2015). https://doi.org/10.1007/s10904-015-0164-y

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  • DOI: https://doi.org/10.1007/s10904-015-0164-y

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