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Synthesis of Mixed-Ligand Zeolitic Imidazolate Framework (ZIF-8-90) for CO2 Adsorption

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Abstract

Microporous metal–organic frameworks (MOFs) exhibit advantages on gas adsorption and catalysis of small molecules owing to high surface area and suitable pore size. One of the members in MOF, zeolitic imidazolate framework (ZIF), has attracted much attention in recent days, and different kinds of ZIFs had been synthesized with single organic linker. However, only few reports discussed the effect of mixed linkers. In this research, we synthesized mixed linker ZIF structure, ZIF-8-90. Different mole percentage of 2-methylimidazole and 2-imidazolecarboxaldehyde were mixed together to form ZIF-8-90 X %. We found that DMF had good effect on controlling the particle size but reducing the productivity ratio. The ZIF-8-90 X % NPs had different physical properties, such as surface area, pore size distribution and gas adsorption. The results showed that ZIF-8-90 30 and 50 % were the better adsorbents for CO2 adsorption (2.37 and 2.82 mol/g, respectively) at room temperature, as compared with other microporous framework, MIL-series, HKUST-1, ZIF-100.

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Acknowledgments

This research was supported by the Ministry of Science and Technology (MOST) of Taiwan (101-2628-E-002-015-MY3, 101-2623-E-002-005-ET and 101-2923-E-002-012-MY3, 103-2632-M-033-001-MY3), and by National Taiwan University. The authors thank Ms. C.-Y. Chein (National Taiwan University) for the assistance in TEM experiments.

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Authors and Affiliations

  1. Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei, 10617, Taiwan

    Yu-Te Liao, Saikat Dutta & Kevin C.-W. Wu

  2. Department of Chemistry, Chung-Yuan Christian University, Chung Li, 32023, Taiwan

    Ching-Hsuan Chien & Chia-Her Lin

  3. R&D Center for Membrane Technology and Department of Chemical Engineering, Chung Yuan University, Chung Li, 32023, Taoyuan, Taiwan

    Chien-Chieh Hu

  4. Department of Chemistry, National Central University, 300 Jhong-Da Road, Chung Li, 32001, Taiwan

    Fa-Kuen Shieh

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  1. Yu-Te Liao
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  2. Saikat Dutta
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  3. Ching-Hsuan Chien
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  4. Chien-Chieh Hu
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  5. Fa-Kuen Shieh
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  6. Chia-Her Lin
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  7. Kevin C.-W. Wu
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Correspondence to Chia-Her Lin or Kevin C.-W. Wu.

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Liao, YT., Dutta, S., Chien, CH. et al. Synthesis of Mixed-Ligand Zeolitic Imidazolate Framework (ZIF-8-90) for CO2 Adsorption. J Inorg Organomet Polym 25, 251–258 (2015). https://doi.org/10.1007/s10904-014-0131-z

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  • DOI: https://doi.org/10.1007/s10904-014-0131-z

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