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Two New Zn(II)/Cd(II) Coordination Polymers Based on Rigid Squaric Acid: Crystal Structure, Topology and Fluorescent Properties

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Abstract

Presented here are two d10 metal–organic coordination polymers (CPs), [Zn(C4O4)0.5(μ 3-OH)] n (1) and [Cd(C4O4)0.5(OX)0.5(H2O)] n (2) (H2OX = oxalic acid) constructed from squaric acid (H2C4O4) tectons. Single-crystal X-ray diffraction studies indicated that both 1 and 2 show 3D structures. The two 3D CPs are assembled from 1D {[Zn(μ 3-OH)] + n } chains to 3D structure linked through C4O4 2− ligands for 1 and 2D {[(Cd1)2(C4O4)]2+} layers pillared by OX2− ligands for 2. The structure of compound 1 can be described as a trinodal (3,6,6)-connected net with the point symbol of {43}2{44·610·8}{45·610}2, whereas 2 possess a trinodal (4,5,6)-connected {42·84} {46·66·83} {48·62}2 topology. Furthermore, the fluorescent and thermal stabilities properties of these two compounds were investigated.

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Acknowledgments

This work was financially supported by the NSF of China (Nos.: 21301106 and 21201109), the NSF of Hubei Province of China (2011CDA118), the Project of Hubei Provincial Education Office (Q20131304).

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Authors and Affiliations

  1. College of Biological and Pharmaceutical Sciences, China Three Gorges University, Yichang, 443002, People’s Republic of China

    Ping Tang & Wei Xia

  2. College of Materials and Chemical Engineering, China Three Gorges University, Yichang, 443002, People’s Republic of China

    Wen-Wen Dong & Jun Zhao

Authors
  1. Ping Tang
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  2. Wen-Wen Dong
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  3. Wei Xia
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  4. Jun Zhao
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Correspondence to Wen-Wen Dong.

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Tang, P., Dong, WW., Xia, W. et al. Two New Zn(II)/Cd(II) Coordination Polymers Based on Rigid Squaric Acid: Crystal Structure, Topology and Fluorescent Properties. J Inorg Organomet Polym 25, 569–575 (2015). https://doi.org/10.1007/s10904-014-0118-9

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  • DOI: https://doi.org/10.1007/s10904-014-0118-9

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