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Synthesis, Structures, and Catalytic Properties of Three New Metal–Organic Coordination Polymers Constructed from Flexible Benzimidazole-Based and cis-1,2-Cyclohexanedicarboxylate Synthons

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Abstract

Three metal–organic coordination polymers {[Co(pbmb)(chadc)]·2H2O} n (1), {[Zn(pbmb)(chadc)]·2H2O} n (2), and [Ag(pbmb)(chadc)] n (3) (pbmb = 1,1′-(1,3-propanediyl)bis(2-methylbenzimidazole), chadc = cis-1,2-cyclohexanedicarboxylate anion), have been hydrothermally synthesized by self-assembly of a flexible bis(2-methylbenzimidazole) ligand and one dicarboxylate anion with three kinds of metal salts. All the compounds were characterized by single-crystal X-ray diffraction and physico-chemical spectroscopic methods. Complexes 1 and 2 possess a 1D sequence of fused rings and 3 shows a 1D helical chain structure, which are bridged by pbmb and chadc ligands. Complex 2 and 3 are further packed into 2D and 3D supramolecular architectures by diverse π–π interactions, respectively. The investigation as heterogeneous catalyst in a Fenton-like process for 1–3 reveals different performances. In addition, the fluorescence properties of 1–3 have been investigated in the solid state.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, 46 West Xinhua Road, Tangshan, 063009, Hebei, People’s Republic of China

    Chun-Lun Ming, Zeng-Chuan Hao & Guang-Hua Cui

  2. Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 S3, 9000, Ghent, Belgium

    Bao-Yi Yu & Kristof Van Hecke

Authors
  1. Chun-Lun Ming
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  2. Zeng-Chuan Hao
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  3. Bao-Yi Yu
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  4. Kristof Van Hecke
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  5. Guang-Hua Cui
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Correspondence to Guang-Hua Cui.

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Ming, CL., Hao, ZC., Yu, BY. et al. Synthesis, Structures, and Catalytic Properties of Three New Metal–Organic Coordination Polymers Constructed from Flexible Benzimidazole-Based and cis-1,2-Cyclohexanedicarboxylate Synthons. J Inorg Organomet Polym 25, 559–568 (2015). https://doi.org/10.1007/s10904-014-0117-x

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  • DOI: https://doi.org/10.1007/s10904-014-0117-x

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