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3D Pillar-Layered Zn(II) Compound with 6-Connected pcu Topology: Synthesis, Structure and Luminescent Properties for Sensing of Nitrobenzene

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Abstract

A new Zn(II) compound, namely {[Zn(atz)(C2O4)0.5]·H2O}n (1 Hatz = 3-amino-1,2,4-triazole), has been synthesized by the hydrothermal reactions of Zn(NO3)2, Hatz and H2C2O4. Single crystal X-ray structure analysis reveals that compound 1 features a 3D porous pillar-layer structure with 6-connected pcu topology. The free water molecules are filled in the 1D channels. Thermal analysis reveals that it can be stable up to 347 °C. Luminescence investigation for 1 reveals that it can be used as a good candidate for sensing of nitrobenzene.

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Acknowledgments

A project supported by scientific research fund of Hebei provincial Science and Technology Department (Grant No. 13227124).

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Authors and Affiliations

  1. College of Sciences, Agricultural University of Hebei, Baoding, 071001, China

    Ying Zhao, Jun-min Wang, Hai-Yan Liu & Shu-Tao Gao

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  1. Ying Zhao
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  2. Jun-min Wang
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  3. Hai-Yan Liu
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  4. Shu-Tao Gao
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Correspondence to Shu-Tao Gao.

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Zhao, Y., Wang, Jm., Liu, HY. et al. 3D Pillar-Layered Zn(II) Compound with 6-Connected pcu Topology: Synthesis, Structure and Luminescent Properties for Sensing of Nitrobenzene. J Inorg Organomet Polym 24, 1027–1031 (2014). https://doi.org/10.1007/s10904-014-0076-2

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  • DOI: https://doi.org/10.1007/s10904-014-0076-2

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