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Sonochemical Synthesis and Structural Characterization and DFT Calculations of a Novel Nano Flower Pb(II) Coordination Compound [Pb(phen)2(4-abs)2]n

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Abstract

Nano-structures of a new coordination polymer of divalent Pb with the ligands 1,10-phenanthroline (phen) and 4-aminobenzene sulfonic acid (4-abs), [Pb(phen)2(4-abs)2]n (1), were synthesized by a sonochemical method that produced a coordination polymer of nanometer size. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction and IR spectroscopy and elemental analysis. Compound 1 was structurally characterized by single crystal X-ray diffraction and showed that the coordination number of the Pb(II) ions is six; i.e. (PbN4O2). Compound 1 also has a stereochemically active lone pair of electrons and a hemi-directed coordination sphere. The chains interact with each other through π–π stacking to create a 3D framework. The structure of 1 was optimized by density functional theory calculations. The calculated structural parameters and IR spectra of 1 are consistent with the crystal structure.

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References

  1. R. Matsuda, R. Kitaura, S. Kitagawa, Y. Kubota, R.V. Belosludov, T.C. Kobayshi, H. Sakamoto, T. Chiba, M. Takata, Y. Kawazoe, Y. Mita, Nature 436, 238 (2005)

    Article  CAS  Google Scholar 

  2. K. Biradha, C.Y. Su, J.J. Vittal, Cryst. Growth Des. 11, 875 (2011)

    Article  CAS  Google Scholar 

  3. B.F. Abrahams, M.J. Grannas, T.A. Hudson, R. Robson, Angew. Chem. Int. Ed. 49(7), 1087 (2010)

    Article  CAS  Google Scholar 

  4. X.-J. Ke, D.-S. Li, M. Du, Inorg. Chem. Commun. 14, 788 (2011)

    Article  CAS  Google Scholar 

  5. X.-Q. Zhao, B. Zhao, S. Wei, P. Cheng, Inorg. Chem. 48, 11048 (2009)

    Article  CAS  Google Scholar 

  6. F. Luo, Y.-X. Che, J.-M. Zheng, Cryst. Growth Des. 9, 1066 (2009)

    Article  CAS  Google Scholar 

  7. D.F. Schriver, P.W. Atkins, Inorganic Chemistry, 3rd edn. (Oxford University Press, New York, 1999)

    Google Scholar 

  8. C. Platas-Iglesias, D. Esteban-Gómez, T. Enriquez-Pérez, F. Avecilla, A. Blas, T. Rodriguez-Blas, Inorg. Chem. 44, 2224 (2005)

    Article  CAS  Google Scholar 

  9. T. Yamaki, K. Nobusada, J. Phys. Chem. A 107, 2351 (2003)

    Article  CAS  Google Scholar 

  10. L. Shimonni-Livny, J.P. Glusker, C.W. Bock, Inorg. Chem. 37, 1853 (1998)

    Article  Google Scholar 

  11. J. Parr, Polyhedron 16, 551 (1997)

    Article  CAS  Google Scholar 

  12. S. Sobanska, J.P. Wignacourt, P. Conflant, M. Drache, M. Lagrenee, E.M. Holt, New J. Chem. 23, 393 (1999)

    Article  CAS  Google Scholar 

  13. E.J. Baran, C.C. Wagner, M. Rossi, F. Caruso, Z. Anorg, Allg. Chem. 626, 701 (2000)

    Article  CAS  Google Scholar 

  14. A.R. Mahjoub, A. Morsali, Polyhedron 21, 1223 (2002)

    Article  CAS  Google Scholar 

  15. S. Taheri, A. Mojidov, A. Morsali, Z. Anorg, Allg. Chem. 633, 1949 (2007)

    Article  CAS  Google Scholar 

  16. A. Aslani, A. Morsali, M. Zeller, Solid State Sci. 10, 1591 (2008). And references therein

    Article  CAS  Google Scholar 

  17. A. Aslani, A. Morsali, M. Zeller, Ultrason. Sonochem 10, 1591 (2008). And references therein

    CAS  Google Scholar 

  18. F. Marandi, B. Mirtamizdoust, A.A. Soudi, H.-K. Fun, Inorg. Chem. Commun. 10, 174 (2007)

    Article  CAS  Google Scholar 

  19. F. Marandi, B. Mirtamizdoust, A.A. Soudi, S. Chantrapromma, H.-K. Fun, Z. Anorg, Allg. Chem. 633, 1329 (2007)

    Article  CAS  Google Scholar 

  20. F. Marandi, B. Mirtamizdoust, A.A. Soudi, V.T. Yilmaz, C. Kazak, Z. Anorg, Allg. Chem. 632, 2380 (2006)

    Article  CAS  Google Scholar 

  21. B. Shaabani, B. Mirtamizdoust, M. Shadman, H.-K. Fun, Z. Anorg. Allg. Chem. 635, 2642 (2009)

    CAS  Google Scholar 

  22. B. Shaabani, B. Mirtamizdoust, D. Viterbo, G. Croce, H. Hammud, P. Hojati-Lalemi, A. Khandar, Z. Anorg. Allg. Chem. 637, 713 (2011)

    Article  CAS  Google Scholar 

  23. B. Mirtamizdoust, B. Shaabani, A. Khandar, H.-K. Fun, S. Huang, M. Shadman, P. Hojati-Lalemi, Z. Anorg. Allg. Chem. 638, 844 (2012)

    Article  CAS  Google Scholar 

  24. Mercury 2.4, Copyright Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK, 2001–2010

  25. A. Altomare, M.C. Burla, M. Camalli, G.L. Cascarano, C. Giacovazzo, A. Guagliardi, A.G. Moliterni, G. Polidori, R. Spagna, J. Appl. Crystallogr. 32, 115 (1999)

    Article  CAS  Google Scholar 

  26. G.M. Sheldrick, A short history of SHELX. Acta Crystallogr. A 64(1), 112 (2007)

    Article  Google Scholar 

  27. L.J. Farrugia, J. Appl. Crystallogr. 30, 565 (1997)

    Article  CAS  Google Scholar 

  28. O.V. Dolomanov, L.J. Bourhis, R.J. Gildea, J.A.K. Howard, H. Puschmann, J. Appl. Cryst. 42, 339 (2009)

    Article  CAS  Google Scholar 

  29. C.A. Hunter, J.K.M. Sanders, J. Am. Chem. Soc. 112, 5525 (1990)

    Article  CAS  Google Scholar 

  30. A.D. Becke, J. Chem. Phys. 98, 5648 (1993)

    Article  CAS  Google Scholar 

  31. C. Lee, W. Yang, R.G. Parr, Phys. Rev. B 37, 785 (1988)

    Article  CAS  Google Scholar 

  32. P.J. Hay, W.R.J. Wadt, Chem. Phys. 82, 270 (1985)

    CAS  Google Scholar 

  33. J.M. Harrowfield, H. Miyamae, B.W. Skelton, A.A. Soudi, A.H. White, Aust. J. Chem. 49, 1165 (1996). And references therein

    Article  Google Scholar 

  34. L.K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds Part B, 5th edn. (Wiley, New York, 1997), pp. 124–126

    Google Scholar 

  35. R.D. Hancock, M.S. Shaikjee, S.M. Dobson, J.C.A. Boeyens, Inorg. Chim. Acta 154, 229 (1998)

    Article  Google Scholar 

  36. N.N. Greenwood, A. Earnshaw, Chemistry of the Elements (Pergamon Press, Oxford, 1986), pp. 235–254

    Google Scholar 

  37. A description of the basis sets and theory level used in this work can be found in the following: Foresman, J. B.; Frisch, A. E. Exploring Chemistry with Electronic Structure Methods, 2nd ed.; Gaussian Inc.: Pittsburgh, PA, 1996

Download references

Acknowledgments

This work is funded by the World Class University Grant KRF R32-2008-000-20082-0 of the National Research Foundation of Korea. The authors acknowledge financial support by University of Tabriz Research Council (project number sad/27/1391-3) and Università del Piemonte Orientale is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Babak Mirtamizdoust, Behrouz Shaabani & Younes Hanifehpour

  2. School of Mechanical Engineering, WCU Nano Research Center, Yeungnam University, Gyongsan, 712-749, South Korea

    Babak Mirtamizdoust, Sang Woo Joo & Younes Hanifehpour

  3. Dipartimento di Scienze e Tecnologie Avanzate, Universitá del Piemonte Orientale, Alessandria, Italy

    Davide Viterbo & Gianluca Croce

Authors
  1. Babak Mirtamizdoust
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  2. Behrouz Shaabani
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  3. Sang Woo Joo
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  4. Davide Viterbo
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  5. Gianluca Croce
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  6. Younes Hanifehpour
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Correspondence to Babak Mirtamizdoust or Sang Woo Joo.

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Mirtamizdoust, B., Shaabani, B., Joo, S.W. et al. Sonochemical Synthesis and Structural Characterization and DFT Calculations of a Novel Nano Flower Pb(II) Coordination Compound [Pb(phen)2(4-abs)2]n . J Inorg Organomet Polym 22, 1397–1403 (2012). https://doi.org/10.1007/s10904-012-9763-z

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  • DOI: https://doi.org/10.1007/s10904-012-9763-z

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