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One-Dimensional Ni(II) and Cu(II) Coordination Polymers Containing Syn-Syn Thiophene-2,5-dicarboxylate and Propane-1,3-diamine

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Abstract

New thiophene-2,5-dicarboxylate complexes with the formula of [M(μ-tdc)(pen)2] n (M = Ni(II) (1) and Cu(II) (2), pen = propane-1,3-diamine, tdc = thiophene-2,5-dicarboxylate) have been synthesized and characterized by using thermal (TG/DTG, DTA and MS) analysis, IR and UV–Vis. spectroscopies, magnetic measurement and single crystal X-Ray diffraction techniques. The Ni(II) and Cu(II) ions are distorted octahedrally coordinated by two oxygen atoms of two bridging thiophene-2,5-dicarboxylate ligands and four nitrogen atoms of the trans-pen ligands. The polymeric chains are connected together by hydrogen bonds interactions, forming three-dimensional network.

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Acknowledgment

This work was supported by the Eskişehir Osmangazi University by Project No. 200819042.

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Authors and Affiliations

  1. Department of Chemistry, Eskişehir Osmangazi University, Faculty of Arts and Sciences, 26480, Eskişehir, Turkey

    Okan Zafer Yeşilel & İnci İlker

  2. Department of Chemistry, Atatürk University, Faculty of Arts and Sciences, 25240, Erzurum, Turkey

    Ertan Şahin

Authors
  1. Okan Zafer Yeşilel
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  2. İnci İlker
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  3. Ertan Şahin
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Correspondence to Okan Zafer Yeşilel.

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Yeşilel, O.Z., İlker, İ. & Şahin, E. One-Dimensional Ni(II) and Cu(II) Coordination Polymers Containing Syn-Syn Thiophene-2,5-dicarboxylate and Propane-1,3-diamine. J Inorg Organomet Polym 21, 103–109 (2011). https://doi.org/10.1007/s10904-010-9414-1

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  • DOI: https://doi.org/10.1007/s10904-010-9414-1

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