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A Colorimetric Fluorescent Probe for SO2 Derivatives-Bisulfite and Sulfite at Nanomolar Level

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Abstract

A colorimetric fluorescent probe with fluorescence emission feature sensitive to SO2 derivatives, i.e. bisulfite (HSO3 −) and sulfite (SO3 2−), was developed based on the HSO3 −/SO3 2−-mediated nucleophilic addition reaction of the probe that. This probe exhibited SO3 2− sensing ability with detection limit down to 46 nM and desired selectivity over other reference anions and redox species. The preliminary fluorescence bioimaging experiments have validated the practicability of the as-prepared probe for SO2 derivatives sensing in living cells.

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Acknowledgements

Financial support from the National Natural Science Foundation of China (grant no. 21373218 and 21573234) is acknowledged.

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Authors and Affiliations

  1. School of Chemistry & Chemical Engineering, University of Chinese Academy of Sciences (UCAS), Beijing, 100049, People’s Republic of China

    Jian Zhang, Yanlin Lv, Yuanlin Zhang, Xuefei Wang & Zhiyuan Tian

  2. College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences (UCAS), Beijing, 100049, People’s Republic of China

    Aidong Peng

  3. Key Laboratory of Green Process and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China

    Guangjin Zhang

Authors
  1. Jian Zhang
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  2. Aidong Peng
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  3. Yanlin Lv
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  4. Yuanlin Zhang
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  5. Xuefei Wang
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  6. Guangjin Zhang
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  7. Zhiyuan Tian
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Corresponding authors

Correspondence to Xuefei Wang, Guangjin Zhang or Zhiyuan Tian.

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Zhang, J., Peng, A., Lv, Y. et al. A Colorimetric Fluorescent Probe for SO2 Derivatives-Bisulfite and Sulfite at Nanomolar Level. J Fluoresc 27, 1767–1775 (2017). https://doi.org/10.1007/s10895-017-2115-1

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  • DOI: https://doi.org/10.1007/s10895-017-2115-1

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