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A Phenanthraquinone Based Fluorescent Probe for Sequential Detection of Cu2+ and SO3 2−

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Abstract

Herein we report the selective detection of Cu2+ and SO3 2− by phenanthraquinone thiosemicarbazone (PQTSC) chemosensor. The chemosensor is efficient in detecting Cu2+ over other metal ions, while the PQTSC-Cu2+ complex selectively sense SO3 2− over other anions. On addition of Cu2+ to the receptor solution, quenching of emission intensity is observed by 16 folds and upon gradual addition of SO3 2− to this solution, the emission intensity increases and the maxima is regained. The limit of detection for Cu2+ detection calculated from fluorescence titration is 1.06 × 10−8 M and the association constant of PQTSC with Cu2+ is found to be 2.18 × 105.

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Acknowledgments

Financial supports received from the Council of Scientific and Industrial Research, New Delhi, India (No. 01(2831)/15/EMR-II) and the Department of Science and Technology, New Delhi, India (No. SB/EMEQ–242/2013) are gratefully acknowledged. S. Gharami is thankful to UGC, India and D. Sarkar is thankful to CSIR, New Delhi, India for their fellowships.

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Kolkata, -700032, India

    Saswati Gharami, Deblina Sarkar, Samik Acharyya & Tapan Kumar Mondal

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  1. Saswati Gharami
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  2. Deblina Sarkar
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  3. Samik Acharyya
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  4. Tapan Kumar Mondal
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Correspondence to Tapan Kumar Mondal.

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Gharami, S., Sarkar, D., Acharyya, S. et al. A Phenanthraquinone Based Fluorescent Probe for Sequential Detection of Cu2+ and SO3 2− . J Fluoresc 26, 2113–2118 (2016). https://doi.org/10.1007/s10895-016-1907-z

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  • DOI: https://doi.org/10.1007/s10895-016-1907-z

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