Abstract
Compact and smooth tungsten coatings on low activation steel substrates were successfully prepared by electrodeposition from Na2WO4–WO3 molten salt at 1173 K in the air. The effects of plating time on the performance of tungsten coating were investigated. The surface morphology showed that tungsten grains changed from the amorphous into regular hexagonal over time. The prepared tungsten coatings were highly (2 1 1)-orientated and exhibited body centered cubic structure via XRD characterization. The thickest tungsten coating (387 ± 15.72 μm) was achieved with the plating time of 40 h. Besides, the tungsten coating displayed acceptable hardness of 389.3 ± 16.8 HV and high adhesive strength to the substrate of 43.39 MPa. Furthermore, the tungsten coatings can stand more than 150 times thermal circles under 773 K, and 20 times under 1023 and 1173 K.
Similar content being viewed by others
References
H. Kim, J. El-Awady, V. Gupta et al., J. Nucl. Mater. 386, 863–865 (2009)
C. Ruset, E. Grigore, H. Maier et al., Fusion Eng. Des. 86, 1677–1680 (2011)
VKh Alimov, B. Tyburska-Püschel, Y. Hatano et al., J. Nucl. Mater. 420, 370–373 (2012)
Y.Y. Lian, X. Liu, Z.K. Cheng et al., J. Nucl. Mater. 455, 371–375 (2014)
M.T. Hosseinnejad, M. Shirazil, Z. Ghorannevis et al., J. Fusion Energ. 31(5), 426–431 (2012)
X. Liu, F. Zhang, S. Tao et al., J. Nucl. Mater. 363, 1299–1303 (2007)
R. Neu, H. Maier, E. Gauthier et al., Phys. Scr. T128, 150–156 (2007)
E. Vassallo, G. Angella, R. Caniello et al., J. Fusion Energ. (2015). doi:10.1007/s10894-015-9945-0
S. Senderoff, G.W. Mellors, Science 153, 1475–1481 (1966)
A. Katagiri, M. Suzuki, Z. Takehara, Electrochem. Soc. 138, 767–773 (1991)
Y.H. Liu, Y.C. Zhang, Q.Z. Liu et al., Int. J. Refract. Met. Hard Mater. 35, 241–245 (2012)
K. Nitta, M. Majima, S. Inazawa et al., Electrochemistry 77, 621–623 (2009)
J. Li, X.Y. Zhang, Y.B. Liu et al., Rare Met. 32, 512–517 (2013)
F. Jiang, Y.C. Zhang, N.B. Sun et al., Appl. Surf. Sci. 317, 867–874 (2014)
V.V. Malyshev, Prot. Met. 37, 216–222 (2001)
B.A.N. Nauka, Electrocrystallization of Metals from Fused Salts (Nauka, Moscow, 1976), p. 280
D.J. Greving, J.R. Shadley, E.F. Rybicki, J. Therm. Spray Technol. 3, 371 (1994)
A. Oliva, R. Kelly, G. Falcone, Surf. Sci. 166, 403–418 (1986)
F.L. Chong, J.L. Chen, J.G. Li et al., J. Nucl. Mater. 375, 213–217 (2008)
F. Jiang, Y.C. Zhang, X.L. Li et al., Fusion Eng. Des. 89, 83–87 (2014)
K.A. Khor, Y.W. Gu, Thin Solid Films 372, 104–113 (2000)
K.A. Khor, Y.W. Gu, Mater. Sci. Eng. A 277, 64–76 (2000)
Acknowledgments
The study was supported by International Thermonuclear Experimental Reactor (ITER) Project of China (No. 2014GB123000).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sun, N., Zhang, Y., Lang, S. et al. Performance of Electrodeposited Tungsten Coating on Low Activation Steel Substrate. J Fusion Energ 34, 1417–1422 (2015). https://doi.org/10.1007/s10894-015-9988-2
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10894-015-9988-2