Abstract
In this present manuscript, ultrasmall copper nanoparticles (UCuNPs) was synthesized by Terminalia bellirica fruit extract as a reducing agent. The method of synthesis is ecofriendly, single step, aqueous and ambient method. As synthesized nanoparticles were in diameter of 2–7 nm. The surface plasmone resonance is observed with UV–visible spectrophotometry, UCuNPs are nonplasmonic. Fourier transform infrared spectroscopy indicates that oxygen-containing functional groups in the T. bellirica fruit extract are involved in the nanoparticle synthesis reaction. High-resolution transmission electron microscopy (HRTEM) was used to confirm that the UCuNPs are spherical shape. XRD analysis confirms that the nanoparticles are single crystalline. X-ray energy dispersive spectroscopy conducted during HRTEM analysis confirms the presence of pure copper in the sample. The particle size analysis is also confirms that the particles were polydispersed. The stability of UCuNPs characterized by zeta potential. We are also done antimicrobial activity (anti bacterial and anti fungal) of UCuNPs shown good activity.
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W. P. McConnell, J. P. Novak, L. C. Brousseau III, R. R. Fuierer, R. C. Tenent, and D. L. Feldheim (2000). J. Phys. Chem. B. 104, 8925.
J. H. Kimand and C. S. Yoon (2008). Thin Solid Films. 516, 4845.
B. Roldan Cuenya (2010). Thin Solid Films. 518, 3127.
K. Tokarek, J. L. Hueso, P. Kustrowski, G. Stochel, and A. Kyziol (2013). Eur. J. Inorg. Chem. 28, 4940.
A. A. Ponce and K. J. Klabunde (2005). J. Mol. Catal. A. 225, 1.
Z. Huang, F. Cui, H. Kang, J. Chen, X. Zhang, and C. Xia (2008). Chem. Mater. 20, 5090.
W. Wei, Y. Lu, W. Chen, and S. Chen (2011). J. Am. Chem. Soc. 133, 2060.
V. D. Cao, P. P. Nguyen, V. Q. Khuong, C. K. Nguyen, X. C. Nguyen, C. H. Dang, and N. Q. Q. Tran (2014). Bull. Korean Chem. Soc. 35, 2645.
Q. Zhang, Z. Yang, B. Ding, X. Lan, and Y. Guo (2010). Trans. Nonferrous Met. Soc. China. 20, 240.
H. R. Ghorbani (2014). Orient. J. Chem. 30, 803.
Z. Cheng, H. Zhong, J. Xu, X. Chu, Y. Song, M. Xu, and H. Huang (2011). Mater. Lett. 65, 3005.
J. N. Solanki, R. Sengupta, and Z. V. P. Murthy (2010). Solid. State. Sciences. 12, 1560.
H. L. Aye, S. Choopun, and T. Chairuangsri (2010). Adv. Mater. Res. 93–94, 83.
B. K. Park, S. Jeong, D. Kim, J. Moon, S. Lim, and J. S. Kim (2007). J. Coll. Int. Sci. 311, 417.
S.-Y. Xie, Z.-J. Ma, C.-F. Wang, S.-C. Lin, Z.-Y. Jiang, R.-B. Huang, and L.-S. Zheng (2004). J. Sol. State Chem. 177, 3743.
D. B. Aaron, A. C. Katelyn, and S. K. St. Angelo (2014). ACS Sust. Chem. Eng. 2, 1933.
G. Chen, H. Qiu, R. Fan, S. Hao, S. Tan, C. Yang, and G. Han (2012). J. Mater. Chem. 22, 20190.
K. Huang, H. Ma, J. Liu, S. Huo, A. Kumar, T. Wei, X. Zhang, S. Jin, Y. Gan, P. C. Wang, S. He, X. Zhang, and X. Liang (2012). ACS Nano. 6, 4483.
A. Leifert, Y. Pan-Bartnek, U. Simon, and W. Jahnen-Dechent (2013). Nanoscale. 5, 6224.
C. P. Khare Indian Medicinal Plants—An Illustrated Dictionary (Springer, New York, 2007).
B. H. Kim, M. J. Hackett, J. Park, and T. Hyeon (2014). Chem. Mater. 26, 59–71.
A. Mao, M. Ding, X. Jin, X. Gu, C. Cai, C. Xin, and T. Zhang (2015). J. Mol. Struct. 1079, 396.
J. Y. Seo, H. W. Kang, D. S. Jung, H. M. Lee, and S. B. Park (2013). Mater. Res. Bull. 48, 1484.
J. J. Brege, C. E. Hamilton, C. A. Crouse, and A. R. Barron (2009). Nano Lett. 9, 2239.
D. Deng, Y. Jin, Y. Cheng, T. Qi, and F. Xiao (2013). Appl. Mater. Interfaces. 5, 3839.
M. N. K. Chowdhury, M. D. H. Beg, M. R. Khan, and M. F. Mina (2013). Mater. Lett. 98, 26.
O. V. Kharissova, B. I. Kharisov, V. Manuel Jimenez-Perez, B. Munoz Flores, and U. Ortiz Mendez (2013). RSC Adv. 3, 22648.
M. Singh, I. Sinhaa, M. Premkumar, A. K. Singh, and R. K. Mandal (2010). Colloids Surf. A. 359, 88.
S. Yallappa, J. Manjanna, M. A. Sindhe, N. D. Satyanarayan, S. N. Pramod, and K. Nagaraja (2013). Spectrochim. Acta Part A. 110, 108.
M. Singh, I. Sinha, M. Premkumar, A. K. Singh, and R. K. Mandal (2010). Colloid Surf. A. 359, 88.
J. Ramyadevi, K. Jeyasubramanian, A. Marikani, G. Rajakumar, and A. A. Rahuman (2012). Mater. Lett. 71, 114.
D. Philip (2011). Spectrochim. Acta A Mol. Biomol. Spectrosc. 78, 327.
Acknowledgments
We gratefully acknowledge the financial support from the University Grant Commission, New Delhi [Grant No. 2-362/2013 (SR)] and special thanks to IIT Madras, Chennai, for the support on instrumental analysis. We are also thankful to Dr. R. V. Jayanth Kasyap, Asst. Professor in English, Yogi Vemana University, Kadapa, India, for verifying the linguistic correctness.
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Viswadevarayalu, A., Venkata Ramana, P., Sreenivasa Kumar, G. et al. Fine Ultrasmall Copper Nanoparticle (UCuNPs) Synthesis by Using Terminalia bellirica Fruit Extract and Its Antimicrobial Activity. J Clust Sci 27, 155–168 (2016). https://doi.org/10.1007/s10876-015-0917-3
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DOI: https://doi.org/10.1007/s10876-015-0917-3