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Synthesis, Structure and Property of a 3D Heterometallic Complex Constructed by Trinuclear [In2Co(OH)2(COO)4] Cluster and BTC Ligand

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Abstract

A novel indium–cobalt heterometallic complex, [C6H11N2]2[In2Co(OH)2 (BTC)2Br2], has been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, XRD, TG-DTA, and single crystal X-ray diffraction. It crystallizes in the monoclinic system with space group P21/c. Its structure is characterized as a 3D open framework constructed by [In2Co(OH)2(COO)4] cluster subunit and the 1,3,5-benzenetricarboxylate ligand. The used IL cations [C6H11N2]+ are located in the channels and compensate for the negative charges of framework. Furthermore, its fluorescent property and ion exchange property have also been studied.

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Acknowledgments

Project supported by Shaanxi Innovative Team of Key Science and Technology (2013KCT-17), and Innovation Funds of Graduate Programs, SNNU (No. 2013CXB022).

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Authors and Affiliations

  1. Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an, 710062, People’s Republic of China

    Sa-Ying Li & Zhi-Hong Liu

  2. Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, Xi’an, 710061, People’s Republic of China

    Sa-Ying Li

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  1. Sa-Ying Li
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  2. Zhi-Hong Liu
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Correspondence to Zhi-Hong Liu.

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Li, SY., Liu, ZH. Synthesis, Structure and Property of a 3D Heterometallic Complex Constructed by Trinuclear [In2Co(OH)2(COO)4] Cluster and BTC Ligand. J Clust Sci 26, 1959–1970 (2015). https://doi.org/10.1007/s10876-015-0889-3

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  • DOI: https://doi.org/10.1007/s10876-015-0889-3

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