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Syntheses, Structures and Properties of Three New Trinuclear Nickel Clusters with (2-Hydroxy-4-methoxyphenyl)-phenyl-methanone

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Abstract

Three new nickel clusters [Ni3(hmpm)4(DMF)2(X)2]·Y (1, X = HCOO−, Y = 0; 2, X = CH3COO−; Y = C5H8; 3, X = F3CCOO−, Y = 0.5H2O, Hhmpm = (2-hydroxy-4-methoxy-phenyl)-phenyl-methanone) have been prepared via solvothermal method. They were characterized by elemental analysis, IR, UV–Vis, fluorescence and X-ray single-crystal diffraction. All three compounds are defined as trinuclear clusters with three nickel atoms linked in line. Herein, we have used three different carboxylate radicals. The results indicate that the steric hindrance effects in carboxylate radicals do not influence the structures of the clusters. The magnetic investigation shows that complexes 1–3 exhibit a ferromagnetic coupling between NiII ions.

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Acknowledgments

This work is financially supported by the National Natural Science Foundation of China (No. 21161006), and Program for Excellent Talents in Guangxi Higher Education Institutions (Gui Jiao Ren [2012]41).

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Authors and Affiliations

  1. College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Shu-Hua Zhang, Wei Wang, Jing-Jing Guo & Hong Hai

  2. Department of Chemical Science and Technology, Kunming University, Kunming, 650214, People’s Republic of China

    Zhehui Weng

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  1. Zhehui Weng
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  2. Shu-Hua Zhang
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Correspondence to Shu-Hua Zhang or Hong Hai.

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Weng, Z., Zhang, SH., Wang, W. et al. Syntheses, Structures and Properties of Three New Trinuclear Nickel Clusters with (2-Hydroxy-4-methoxyphenyl)-phenyl-methanone. J Clust Sci 26, 1129–1142 (2015). https://doi.org/10.1007/s10876-014-0802-5

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