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Derivatives of Bis(diphenylphosphino)maleic Anhydride as Ligands in Polynuclear Gold(I) Complexes

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Abstract

Based on the new binuclear gold(I) complex [(AuCl)2(L1)] (1) (L1 = 2,3-bis(diphenylphosphino)maleic anhydride) four new polynuclear compounds were synthesized by reactions of 1 with E(SiMe3)2 (E = S, Se). During the formation of these new compounds the initial ligand L1 undergoes various transformations (e.g. substitution, hydration or hydrogenation) leading to the new ligands: trans-2,3-bis(diphenylphosphino)succinic anhydride (L2), 2-diphenylphosphino-3-mercapto-maleic anhydride anion (L3), 2-diphenylphosphino-3-selenolato-maleic anhydride anion (L4) and 2,3-bis(diphenylphosphino)succinic acid (L5). In case of using the sulfur species S(SiMe3)2 a pentanuclear cluster, [Au5(PPh2)3(L3)2] (2), and a 24-nuclear cluster, [Au24S6(PPh2)4(L3)8] (3), could be obtained. With Se(SiMe3)2 the binuclear complex, [(AuCl)2(L2)] (4), and the dodecanuclear cluster, [Au12Se4(L4)4(L5)2] (5), were yielded.

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Acknowledgments

The authors are thankful to the DFG-Center for Functional Nanostructures (CFN) for financial support.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesser Str. 15, 76131, Karlsruhe, Germany

    Wen Yu & Dieter Fenske

  2. Center for Functional Nanostructures (CFN), Karlsruhe Institute of Technology (KIT), Wolfgang-Gaede-Str. 1a, 76131, Karlsruhe, Germany

    Wen Yu, Olaf Fuhr & Dieter Fenske

  3. Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, Blgd. 640, 76344, Eggenstein-Leopoldshafen, Germany

    Olaf Fuhr & Dieter Fenske

Authors
  1. Wen Yu
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  2. Olaf Fuhr
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Correspondence to Olaf Fuhr or Dieter Fenske.

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Dedicated to Prof. Rick Adams on the occasion of his 65th birthday.

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Yu, W., Fuhr, O. & Fenske, D. Derivatives of Bis(diphenylphosphino)maleic Anhydride as Ligands in Polynuclear Gold(I) Complexes. J Clust Sci 23, 753–766 (2012). https://doi.org/10.1007/s10876-012-0487-6

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  • DOI: https://doi.org/10.1007/s10876-012-0487-6

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