Abstract
The title compound, hydantoin-l-proline, C6H8N2O2, crystallize in the orthorhombic system with space group P212121 (N°19), Z = 4, and unit cell parameters a = 7.136(1) Å, b = 8.009(2) Å, c = 11.378(2) Å. The molecular structure shows a hydantoin and pyrrolidine ring coupling forming a bicyclohydantoin. The crystal packing is governed by N–H···O hydrogen bond-type intermolecular interactions, forming infinite one-dimensional chains.
Graphical Abstract
In the crystal structure of hydantoin-l-proline, a bicyclohydantoin, the molecules are linked by N–H···O hydrogen bonds, forming infinite one-dimensional zigzag chains, running along [010] plane, with a C(4) graph-set motif.
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Acknowledgments
This work was supported by CDCHT-ULA (Grant C-1755-11-08-B) and FONACIT (Grant LAB-97000821). The authors also thank to MSc. Teresa González and Dr. A. Briceño, IVIC, Venezuela, for data collection.
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Delgado, G.E., Seijas, L.E. & Mora, A.J. Synthesis and Crystal Structure Determination of Hydantoin-l-Proline. J Chem Crystallogr 42, 968–971 (2012). https://doi.org/10.1007/s10870-012-0344-3
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DOI: https://doi.org/10.1007/s10870-012-0344-3