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Synthesis and Single Crystal X-Ray Structure of [Na(H2O)2(C18H15O6SO3)]2

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Abstract

[Na(H2O)2(C18H15O6SO3)]2 was synthesized by sulfated 5-hydroxy-6,7,4′-trimethoxyisoflavone with concentrated sulfuric acid. Single-crystal X-ray diffraction study indicates that it is a dimeric centrosymmetric species. The coordination polyhedron of each Na(I) atom exhibits a distorted trigonal bipyramidal geometry. The dimeric units are linked by intermolecular hydrogen bonds C–H⋯π, C–H⋯O and O–H⋯O to result in a three-dimensional framework.

Graphical Abstract

[Na(H2O)2(C18H15O6SO3)]2 was synthesized by sulfated 5-hydroxy-6,7,4′-trimethoxyisoflavone with concentrated sulfuric acid. The coordination polyhedron of each Na(I) atom exhibits a distorted trigonal bipyramidal geometry. The dimeric centrosymmetric units are linked by intermolecular hydrogen bonds C–H⋯π, C–H⋯O and O–H⋯O to result in a three-dimensional framework.

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Acknowledgments

We thank the Science and Technology Key Project of Education Ministry, P. R. China (No: 107138) for financial support.

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Authors and Affiliations

  1. Key Laboratory of Medicinal Plant Resources and Natural Pharmaceutical Chemistry (Shaanxi Normal University), Ministry of Education, Xi’an, 710062, People’s Republic of China

    Xue-Ling Zhang, Zun-Ting Zhang & Yong Liang

  2. School of Chemistry and Materials Science, Shaanxi Normal University, Xi’an, 710062, People’s Republic of China

    Xue-Ling Zhang, Zun-Ting Zhang & Yong Liang

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  1. Xue-Ling Zhang
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  2. Zun-Ting Zhang
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  3. Yong Liang
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Correspondence to Zun-Ting Zhang.

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Zhang, XL., Zhang, ZT. & Liang, Y. Synthesis and Single Crystal X-Ray Structure of [Na(H2O)2(C18H15O6SO3)]2 . J Chem Crystallogr 38, 861–865 (2008). https://doi.org/10.1007/s10870-008-9406-y

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  • DOI: https://doi.org/10.1007/s10870-008-9406-y

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