Skip to main content
Log in

Variation of the photocatalytic performance of decorated MWCNTs (MWCNTs-ZnO) with pH for photo degradation of methyl orange

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this work, we reported the variation of the photo degradation of methyl orange with pH using three kinds of MWCNTs-ZnO hybrids. The obtained results exhibit that the removal efficiency of methyl orange using all applied photocatalysts increases by increasing the irradiation time. Meanwhile, the results show that the augmentation of the MWCNTs content in the synthesized photocatalysts from 0.02 to 0.06 g leads to the increment of the photo decomposition of methyl orange. Also, the photocatalytic activity of studied decorated MWCNTs show that the removal efficiency of methyl orange at acidic condition (pH = 4) is higher than that of neutral (pH = 7) and basic (pH = 10) condition. The photocatalytic activity of all studied decorated MWCNTs can be predicted by proposed models with accuracy up to 98%. The results of Duncan’s multiple range test at 5% level of probability reveal that the variation of pH in three studied levels (4, 7 and 10) provides a reasonable effect on the removal efficiency of pollutant.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. S. Abbasi, M. Hasanpour, The effect of pH on the photocatalytic degradation of methyl orange using decorated ZnO nanoparticles with SnO2 nanoparticles. J. Mater. Sci. 28(2), 1307–1314 (2017)

    Google Scholar 

  2. A. Ayati, A. Ahmadpour, F.F. Bamoharram, B. Tanhaei, M. Mänttäri, M. Sillanpää, A review on catalytic applications of Au/TiO2 nanoparticles in the removal of water pollutant. Chemosphere 107, 163–174 (2014)

    Article  Google Scholar 

  3. A. Ghaderi, S. Abbasi, F. Farahbod, Synthesis of SnO2 and ZnO nanoparticles and SnO2–ZnO hybrid for the photocatalytic oxidation of methyl orange. Iran. J. Chem. Eng. 12(3), 96–105 (2015)

    Google Scholar 

  4. H. Yuan, J. Xu, Preparation, characterization and photocatalytic activity of nanometer SnO2. Int. J. Chem. Eng. Appl. 1(3), 214–246 (2010)

    Google Scholar 

  5. L.G. Devi, K.M. Reddy, Enhanced photocatalytic activity of silver metallized TiO2 particles in the degradation of an azo dye methyl orange: characterization and activity at different pH values. Appl. Surf. Sci. 256, 3116–3121 (2010)

    Article  Google Scholar 

  6. G. Yang, Z. Yan, T. Xiao, Preparation and characterization of SnO2/ZnO/TiO2 composite semiconductor with enhanced photocatalytic activity. Appl. Surf. Sci. 258, 8704–8712 (2012)

    Article  Google Scholar 

  7. H. Tada, T. Kiyonaga, S.I. Naya, Rational design and applications of highly efficient reaction systems photocatalyzed by noble metal nanoparticle-loaded titanium(IV) dioxide. Chem. Soc. Rev. 38, 1849–1858 (2009)

    Article  Google Scholar 

  8. S.G. Kumar, L.G. Devi, Review on modified TiO2 photocatalysis under UV/visible light: selected results and related mechanisms on interfacial charge carrier transfer dynamics. J. Phys. Chem. A 115, 13211–13241 (2011)

    Article  Google Scholar 

  9. K. Byrappa, A.S. Dayananda, C.P. Sajan, B. Basavalingu, M.B. Shayan, K. Soga, M. Yoshimura, Hydrothermal preparation of ZnO:CNT and TiO2:CNT composites and their photocatalytic applications. J. Mater. Sci. 43, 2348–2355 (2008)

    Article  Google Scholar 

  10. Q. Wang, D. Yang, D. Chen, Y. Wang, Z. Jiang, Synthesis of anatase titania-carbon nanotubes nanocomposites with enhanced photocatalytic activity through a nanocoating-hydrothermal process. J. Nanopart. Res. 9, 1087–1096 (2007)

    Article  Google Scholar 

  11. S. Abbasi, S.M. Zebarjad, S.H.N. Baghban, Decorating and filling of multi-walled carbon nanotubes with TiO2 nanoparticles via wet chemical method. Engineering 5, 207–212 (2013)

    Article  Google Scholar 

  12. S. Abbasi, S.M. Zebarjad, S.H.N. Baghban, A. Youssefi, Statistical analysis of thermal conductivity of nanofluid containing decorated multi-walled carbon nanotubes with TiO2 nanoparticles. Bull. Mater. Sci. 37(6), 1439–1445 (2014)

    Article  Google Scholar 

  13. S. Abbasi, S.M. Zebarjad, S.H.N. Baghban, A. Youssefi, Synthesis of TiO2 nanoparticles and decorated multiwalled carbon nanotubes with various content of rutile titania. Synth. React. Inorg. Met.-Org. Nano-Met. Chem. 45, 1539–1548 (2015)

    Article  Google Scholar 

  14. C. Ming-liang, Z. Feng-jun, W.-c. Oh, Synthesis, characterization, and photocatalytic analysis of CNT/TiO2 composites derived from MWCNTs and titanium sources. New Carbon Mater. 24(2), 159–166 (2009)

    Article  Google Scholar 

  15. G. Zhu, H. Wang, G. Yang, L. Chen, P. Guo, L. Zhang, A facile synthesis of ZnO/CNTs hierarchical mircosphere composites with enhanced photocatalytic degradation of methylene blue. R. Soc. Chem. 5, 72476–72481 (2015). doi:10.1039/C5RA11873E

    Google Scholar 

  16. H. Bai, X. Zan, L. Zhang, D.D. Sun, Multi-functional CNT/ZnO/TiO2 nanocomposite membrane for concurrent filtration and photocatalytic degradation. Sep. Purif. Technol. 156, 922–930 (2015)

    Article  Google Scholar 

  17. L. Wang, L. Shen, L. Zhu, H. Jin, N. Bing, L. Wang, Preparation and photocatalytic properties of SnO2 coated on Nitrogen-doped carbon nanotubes. J. Nanomater. 2012, 1–6 (2011)

    Google Scholar 

  18. N. Bouazza, M. Ouzzine, M.A.L.-R. Denas, D. Eder, A. Linares-Solano, TiO2 nanotubes and CNT–TiO2 hybrid materials for the photocatalytic oxidation of propene at low concentration. Appl. Catal. B 92, 377–383 (2009)

    Article  Google Scholar 

  19. M. Ahmad, E. Ahmed, Z.L. Hong, W. Ahmed, A. Elhissi, N.R. Khalid, Photocatalytic, sonocatalytic and sonophotocatalytic degradation of rhodamine B using ZnO/CNTs composites photocatalysts. Ultrason. Sonochem. (2013). doi:10.1016/j.ultsonch.2013.08.014

    Google Scholar 

  20. W. Xuejing, Y. Shuwen, L. Xiaobo, Sol-gel Preparation of CNT/ZnO nanocomposite and its photocatalytic property. Chin. J. Chem. 27, 1317–1320 (2009)

    Article  Google Scholar 

  21. S. Abbasi, S.M. Zebarjad, S.H.N. Baghban, A. Youssefi, M.-S. Ekrami-Kakhki, Experimental investigation of the rheological behavior and viscosity of decorated multi-walled carbon nanotubes with TiO2 nanoparticles/water nanofluids. J. Therm. Anal. Calorim. (2015). doi:10.1007/s10973-015-4878-4

    Google Scholar 

  22. S. Abbasi, S.M. Zebarjad, S.H.N. Baghban, A. Youssefi, M.-S. Ekrami-Kakhki, Thermal conductivity ofwater based nanofluids containing decorated multi walled carbon nanotubes with different amount of TiO2 nanoparticles. Iran. J. Chem. Eng. 12(1), 30–41 (2015)

    Google Scholar 

  23. N. Roozban, S. Abbasi, M. Ghazizadeh, Statistical analysis of the photocatalytic activity of decorated multi-walled carbon nanotubes with ZnO nanoparticles. J Mater. Sci. 28(8), 6047–6055 (2017). doi:10.1007/s10854-016-6280-9

    Google Scholar 

  24. N. Roozban, S. Abbasi, M. Ghazizadeh, The experimental and statistical investigation of the photo degradation of methyl orange using modified MWCNTs with different amount of ZnO nanoparticles”, J Mater. Sci. (2017). doi:10.1007/s10854-017-6421-9

    Google Scholar 

  25. L. Chen, T.T. T., C.A.. Huang, J. Li, L. Yuan, Q. Cai, Synthesis and photocatalytic application of Au/Ag nanoparticle-sensitized ZnO films. Appl. Surf. Sci. 273, 82–88 (2013)

    Article  Google Scholar 

  26. H.C. Huang, G.L. Huang, H.L. Chen, Y.D. Lee, Immobilization of TiO2 nanoparticles on carbon nanocapsules for photovoltaic applications. Thin Solid Films 511–512, 203–207 (2006)

    Article  Google Scholar 

  27. S.H. Borji, S. Nasseri, R. Nabizadeh, A.H. Mahvi, A.H. Javadi, Photocatalytic degradation of phenol in aqueous solutions by Fe(III)-doped TiO2/UV process. Iran. J. Health Environ. 3(4), 369–380 (2011)

    Google Scholar 

  28. M. Namvar-Mahboub, M. Pakizeh, Optimization of preparation conditions of polyamide thin film composite membrane for organic solvent nanofiltration. Korean J. Chem. Eng. 31(2), 327–337 (2014)

    Article  Google Scholar 

  29. A. Kazemi-Beydokhti, H.A. Namaghi, M.A.H. Asgarkhani, S.Z. Heris, Prediction of stability and thermal conductivity of SnO2 nanofluid via statistical method and an artificial neural network. Braz. J. Chem. Eng. 32(4), 903–917 (2015)

    Article  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the help given by head of Central Research Nano Laboratory of Esfarayen University of Technology.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sedigheh Abbasi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abbasi, S., Hasanpour, M. Variation of the photocatalytic performance of decorated MWCNTs (MWCNTs-ZnO) with pH for photo degradation of methyl orange. J Mater Sci: Mater Electron 28, 11846–11855 (2017). https://doi.org/10.1007/s10854-017-6992-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-6992-5

Keywords

Navigation