Abstract
In this work, (K0.5Na0.5)(Nb0.96Sb0.04)O3–Bi0.5Na0.5ZrO3–Bi0.5Li0.5ZrO3 lead-free ceramics were fabricated by the conventional solid-state method, and effects of Bi0.5Li0.5ZrO3 on their phase structure and electrical properties were studied. Their piezoelectric properties are sensitive to the addition of Bi0.5Li0.5ZrO3 as well as its contents. The addition of Bi0.5Li0.5ZrO3 simultaneously increased their Curie temperature and decreased rhombohedral and tetragonal phase transition temperature. Their dielectric, ferroelectric, and piezoelectric properties were strongly dependent on Bi0.5Li0.5ZrO3 contents. With increasing Bi0.5Li0.5ZrO3 contents, their dielectric loss can be decreased, and their k p and P r values can be further optimized. However, their ε r and d 33 slightly decreased with the increase of Bi0.5Li0.5ZrO3 contents due to the deviation of rhombohedral and tetragonal phase boundary, and the ceramics with x ≤ 0.2 exhibited a high d 33 of >410 pC/N. As a result, this work could further understand the role of Bi0.5Li0.5ZrO3 in electrical properties of high-performance alkali niobate ceramics.
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References
J. Wu, D. Xiao, J. Zhu, Potassium–sodium niobate lead-free piezoelectric materials: past, present, and future of phase boundaries. Chem. Rev. 115, 2559 (2015)
Y. Guo, K. Kakimoto, H. Ohsato, Phase transitional behavior and piezoelectric properties of (Na0.5K0.5)NbO3–LiNbO3 ceramics. Appl. Phys. Lett. 85, 4121 (2004)
K. Wang, J.F. Li, Domain engineering of lead-free Li-modified (K, Na)NbO3 polycrystals with highly enhanced piezoelectricity. Adv. Funct. Mater. 20(12), 1924 (2010)
J.G. Wu, D. Xiao, Y. Wang, J. Zhu, P. Yu, Effects of K content on the dielectric, piezoelectric, and ferroelectric properties of 0.95(KxNa1−x)NbO3–0.05LiSbO3 lead-free ceramics. J. Appl. Phys. 103, 024102 (2008)
S.J. Zhang, R. Xia, T.R. Shrout, G. Zang, J. Wang, Piezoelectric properties in perovskite 0.948(K0.5Na0.5)NbO3–0.052LiSbO3 lead-free ceramics. J. Appl. Phys. 100, 104108 (2006)
Z. Shen, K. Wang, J. Li, Combined effects of Li content and sintering temperature on polymorphic phase boundary and electrical properties of Li/Ta co-doped (Na, K)NbO3 lead-free piezoceramics. Appl. Phys. A 97, 911 (2009)
E. Hollenstein, M. Davis, D. Damjanovic, N. Setter, Piezoelectric properties of Li-and Ta-modified (K0.5Na0.5)NbO3 ceramics. Appl. Phys. Lett. 87(18), 182905 (2005)
Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamura, Lead-free piezoceramics. Nature 432, 84 (2004)
Y. Gao, J. Zhang, Y. Qing, Y. Tan, Z. Zhang, X. Hao, Remarkably strong piezoelectricity of lead-free (K0.45Na0.55)0.98Li0.02(Nb0.77Ta0.18Sb0.05)O3 Ceramic. J. Am. Ceram. Soc. 94(9), 2968 (2011)
R. Zuo, J. Fu, D. Lv, Phase transformation and tunable piezoelectric properties of lead-free (Na0.52K0.48−xLix)(Nb1−x−ySbyTax)O3 system. J. Am. Ceram. Soc. 92(1), 283 (2009)
J.G. Wu, D.Q. Xiao, Y.Y. Wang, J.G. Zhu, L. Wu, Y.H. Jiang, Effects of K/Na ratio on the phase structure and electrical properties of (KxNa0.96−xLi0.04)(Nb0.91Ta0.05Sb0.04)O3 lead-free ceramics. Appl. Phys. Lett. 91(25), 252907 (2007)
X. Li, J. Zhu, M. Wang, Y. Luo, W. Shi, L. Li, J. Zhu, D. Xiao, BiScO3-modified (K0.475Na0.475Li0.05)(Nb0.95Sb0.05)O3 lead-free piezoelectric ceramics. J. Alloys Compd. 499, L1 (2010)
M. Jiang, M. Deng, H. Lu, S. Wang, X. Liu, Piezoelectric and dielectric properties of K0.5Na0.5NbO3–LiSbO3–BiScO3 lead-free piezoceramics. Mater. Sci. Eng. B 176, 167 (2011)
X. Cheng, J. Wu, X. Wang, B. Zhang, J. Zhu, D. Xiao, X. Wang, X. Lou, Giant d 33 in (K, Na)(Nb, Sb)O3–(Bi, Na, K, Li) ZrO3 based lead-free piezoelectrics with high Tc. Appl. Phys. Lett. 103, 052906 (2013)
T. Zheng, J. Wu, X. Cheng, X. Wang, B. Zhang, D. Xiao, J. Zhu, X. Lou, X. Wang, New potassium–sodium niobate material system: a giant-d 33 and high-T C lead-free piezoelectric. Dalton Trans. 43, 11759 (2014)
D. Xiao, J. Wu, L. Wu, J. Zhu, P. Yu, D. Lin, Y. Liao, Y. Sun, Investigation on the composition design and properties study of perovskite lead-free piezoelectric ceramics. J. Mater. Sci. 44, 5408 (2009)
K. Xu, J. Li, X. Lv, J. Wu, X. Zhang, D. Xiao, J. Zhu, Superior piezoelectric properties in potassium-sodium niobate lead-free ceramics. Adv. Mater. 28(38), 8519 (2016)
T. Zheng, J. Wu, Relationship between poling characteristics and phase boundaries of potassium-sodium niobate ceramics. ACS Appl. Mater. Interfaces 8(14), 9242 (2016)
J.F. Li, K. Wang, F.Y. Zhu, L.Q. Cheng, F.Z. Yao, (K, Na) NbO3-Based lead-free piezoceramics: fundamental aspects, processing technologies, and remaining challenges. J. Am. Ceram. Soc. 96(12), 3677 (2013)
X. Wang, J. Wu, D. Xiao, J. Zhu, X. Cheng, T. Zheng, B. Zhang, X. Lou, X. Wang, Giant piezoelectricity in potassium–sodium niobate lead-free ceramics. J. Am. Chem. Soc. 136(7), 2905 (2014)
Z.P. Yang, Y.F. Chang, L.L. Wei, Phase transitional behavior and electrical properties of lead-free (K0.44Na0.52Li0.04)(Nb0.96−xTaxSb0.04)O3 piezoelectric ceramics. Appl. Phys. Lett. 90(4), 042911 (2007)
J.L. Zhang, X.J. Zong, L. Wu, Y. Gao, P. Zheng, S.F. Shao, Polymorphic phase transition and excellent piezoelectric performance of (K0.55Na0.45)0.965Li0.035Nb0.80Ta0.20O3 lead-free ceramics. Appl. Phys. Lett. 95, 022909 (2009)
D. Lin, K.W. Kwok, H.L.W. Chan, Microstructure, phase transition, and electrical properties of (K0.5Na0.5)1−xLix(Nb1−yTay)O3 lead-free piezoelectric ceramics. J. Appl. Phys. 102, 034102 (2007)
R.P. Wang, H. Bando, T. Katsumata, Y. Inaguma, H. Taniguchi, M. Itoh, Tuning the orthorhombic–rhombohedral phase transition temperature in sodium potassium niobate by incorporating barium zirconate. Phys. Status Solidi RRL 3(5), 142 (2009)
B. Zhang, J. Wu, X. Cheng, X. Wang, D. Xiao, J. Zhu, X. Wang, X. Lou, Lead-free piezoelectrics based on potassium–sodium niobate with giant d 33. ACS Appl. Mater. Interfaces 5(16), 7718 (2013)
P. Zhao, B.P. Zhang, J.F. Li, High piezoelectric d 33 coefficient in Li-modified lead-free (Na, K)NbO3 ceramics sintered at optimal temperature. Appl. Phys. Lett. 90, 242909 (2007)
Y. Chang, Z. Yang, L. Xiong, Z. Liu, Z. Wang, Phase structure, microstructure, and electrical properties of Sb-modified (K, Na, Li)(Nb, Ta)O3 piezoelectric ceramics. J. Am. Ceram. Soc. 91(7), 2211 (2008)
J. Hao, Z. Xu, R. Chu, Y. Zhang, Q. Chen, P. Fu, W. Li, G. Li, Q. Yin, Characterization of (K0.5Na0.5) NbO3 powders and ceramics prepared by a novel hybrid method of sol–gel and ultrasonic atomization. Mater. Design 31, 3146 (2010)
T. Chen, H. Wang, T. Zhang, G. Wang, J. Zhou, J. Zhang, Y. Liu, Piezoelectric behavior of (1 − x)K0.50Na0.50NbO3–xBa0.80Ca0.20ZrO3 lead-free ceramics. Ceram. Int. 39, 6619 (2013)
J. Wu, Z. Fan, D. Xiao, J. Zhu, J. Wang, Multiferroic Bismuth Ferrite-based materials for multifunctional applications: ceramic bulks, thin films and nanostructures. Prog. Mater. Sci. 84, 335 (2016)
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Authors gratefully acknowledge the supports of the Chengdu Medical College and the Scientific Research Foundation of the Education Department of Sichuan Province, China (14Z057).
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Mei, T., Chen, T., Liu, Y. et al. Composition dependence of phase boundary and electrical properties in lead-free (K0.5Na0.5)(Nb0.96Sb0.04)O3–Bi0.5Na0.5ZrO3–Bi0.5Li0.5ZrO3 ceramics. J Mater Sci: Mater Electron 28, 4879–4884 (2017). https://doi.org/10.1007/s10854-016-6135-4
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DOI: https://doi.org/10.1007/s10854-016-6135-4