Abstract
The fabrication of advanced oil/water separation materials with integrated properties of mechanical robust, high efficiency, and low cost is a long-standing challenge. O-SM/ALG (octadecylamine modified silk microfibers/calcium alginate) sponges were synthesized in this paper through a facile process. The as-fabricated O-SM/ALG sponges possess interconnected porous structure, high mechanical durability, hydrophobicity, and lipophilicity that favored for oil/water separation. As oil absorbents, the O-SM/ALG sponges displayed excellent water repellence, exhibited high absorption capacity for various oils and organic solvents (the saturated absorption capacity was 13.1–24.6 times of its own weight), and showed good recyclability (reused > 20 cycles with remained high absorption efficiency). Furthermore, the O-SM/ALG sponges could also be applied as a filter to effectively and selectively separate oils from the oil/water mixture, being a promising candidate for the treatment of oily wastewater.
Similar content being viewed by others
References
Gore PM, Naebe M, Wang X, Kandasubramanian B (2022) J Hazard Mater 426:127822. https://doi.org/10.1016/j.jhazmat.2021.127822
Zhou J, Zhang Y, Yang Y, Chen Z, Jia G, Zhang L (2019) Appl Surf Sci 497:143762. https://doi.org/10.1016/j.apsusc.2019.143762
Liu Q, Liu Y, Feng Q, Chen C, Xu Z (2023) J Hazard Mater 441:129965. https://doi.org/10.1016/j.jhazmat.2022.129965
Sam EK, Liu J, Lv XM (2021) Ind Eng Chem Res 60:2353–2364. https://doi.org/10.1021/acs.iecr.0c05906
Zhang HQ, Jin Y, Chi C et al (2021) Biomaterials 273:120824. https://doi.org/10.1016/j.biomaterials.2021.120824
Guo B, Dong R, Liang Y, Li M (2021) Nat Rev Chem 5:773–791. https://doi.org/10.1038/s41570-021-00323-z
Lerdchai K, Kitsongsermthon J, Ratanavaraporn J, Kanokpanont S, Damrongsakkul S (2016) J Pharm Sci 105:221. https://doi.org/10.1002/jps.24701
Patil PP, Reagan MR, Bohara RA (2020) Int J Biol Macromol 164:4613–4627. https://doi.org/10.1016/j.ijbiomac.2020.08.041
Hadji EM, Fu B, Abebe A, Bilal HM, Wang J (2020) Front Chem Sci Eng 14:749. https://doi.org/10.1007/s11705-019-1890-4
Yang J, Chen Y, Gao K et al (2021) Carbohydr Polym 272:118527. https://doi.org/10.1016/j.carbpol.2021.118527
Phanthong P, Reubroycharoen P, Kongparakul S et al (2018) Carbohydr Polym 190:184–189. https://doi.org/10.1016/j.carbpol.2018.02.066
Gore PM, Naebe M, Wang X, Kandasubramanian B (2019) Chem Eng J 374:437–470. https://doi.org/10.1016/j.cej.2019.05.163
Shome A, Moses JC, Rather AM, Mandal BB, Manna U (2021) ACS Appl Mater Interfaces 13:24258–24271. https://doi.org/10.1021/acsami.1c03150
Peng M, Zhu Y, Li H et al (2019) Chem Eng J 373:213–226. https://doi.org/10.1016/j.cej.2019.05.013
Fürtauer S, Hassan M, Elsherbiny A, Gabal SA, Mehanny S, Abushammala H (2021) Polymers 13:2739
Patowary M, Pathak K, Ananthakrishnan R (2016) RSC Adv 6:73660–73667. https://doi.org/10.1039/c6ra14723b
Maleki H, Whitmore L, Hüsing N (2018) J Mater Chem A 6:12598–12612. https://doi.org/10.1039/c8ta02821d
Guan H, Cheng ZY, Wang XQ (2018) ACS Nano 12:10365–10373. https://doi.org/10.1021/acsnano.8b05763
Guo Z, Long B, Gao S et al (2021) J Hazard Mater 402:123838. https://doi.org/10.1016/j.jhazmat.2020.123838
Wu X, Lei Y, Li S et al (2021) J Hazard Mater 403:124090. https://doi.org/10.1016/j.jhazmat.2020.124090
Acknowledgments
This work was supported by Talent Foundation funded by Province and Ministry Co-construction Collaborative Innovation Center of Eco-chemical Engineering (No. STHGYX2206).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no competing financial interest.
Additional information
Handling Editor: Stephen Eichhorn.
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Zhao, S., Liu, K. & Wu, X. Composite sponges fabricated by silk fibers and alginate for efficient oil/water separation. J Mater Sci 58, 457–465 (2023). https://doi.org/10.1007/s10853-022-08030-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-022-08030-w