Skip to main content
Log in

Composite sponges fabricated by silk fibers and alginate for efficient oil/water separation

  • Polymers & biopolymers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The fabrication of advanced oil/water separation materials with integrated properties of mechanical robust, high efficiency, and low cost is a long-standing challenge. O-SM/ALG (octadecylamine modified silk microfibers/calcium alginate) sponges were synthesized in this paper through a facile process. The as-fabricated O-SM/ALG sponges possess interconnected porous structure, high mechanical durability, hydrophobicity, and lipophilicity that favored for oil/water separation. As oil absorbents, the O-SM/ALG sponges displayed excellent water repellence, exhibited high absorption capacity for various oils and organic solvents (the saturated absorption capacity was 13.1–24.6 times of its own weight), and showed good recyclability (reused > 20 cycles with remained high absorption efficiency). Furthermore, the O-SM/ALG sponges could also be applied as a filter to effectively and selectively separate oils from the oil/water mixture, being a promising candidate for the treatment of oily wastewater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8

Similar content being viewed by others

References

  1. Gore PM, Naebe M, Wang X, Kandasubramanian B (2022) J Hazard Mater 426:127822. https://doi.org/10.1016/j.jhazmat.2021.127822

    Article  CAS  Google Scholar 

  2. Zhou J, Zhang Y, Yang Y, Chen Z, Jia G, Zhang L (2019) Appl Surf Sci 497:143762. https://doi.org/10.1016/j.apsusc.2019.143762

    Article  CAS  Google Scholar 

  3. Liu Q, Liu Y, Feng Q, Chen C, Xu Z (2023) J Hazard Mater 441:129965. https://doi.org/10.1016/j.jhazmat.2022.129965

    Article  CAS  Google Scholar 

  4. Sam EK, Liu J, Lv XM (2021) Ind Eng Chem Res 60:2353–2364. https://doi.org/10.1021/acs.iecr.0c05906

    Article  CAS  Google Scholar 

  5. Zhang HQ, Jin Y, Chi C et al (2021) Biomaterials 273:120824. https://doi.org/10.1016/j.biomaterials.2021.120824

    Article  CAS  Google Scholar 

  6. Guo B, Dong R, Liang Y, Li M (2021) Nat Rev Chem 5:773–791. https://doi.org/10.1038/s41570-021-00323-z

    Article  CAS  Google Scholar 

  7. Lerdchai K, Kitsongsermthon J, Ratanavaraporn J, Kanokpanont S, Damrongsakkul S (2016) J Pharm Sci 105:221. https://doi.org/10.1002/jps.24701

    Article  CAS  Google Scholar 

  8. Patil PP, Reagan MR, Bohara RA (2020) Int J Biol Macromol 164:4613–4627. https://doi.org/10.1016/j.ijbiomac.2020.08.041

    Article  CAS  Google Scholar 

  9. Hadji EM, Fu B, Abebe A, Bilal HM, Wang J (2020) Front Chem Sci Eng 14:749. https://doi.org/10.1007/s11705-019-1890-4

    Article  CAS  Google Scholar 

  10. Yang J, Chen Y, Gao K et al (2021) Carbohydr Polym 272:118527. https://doi.org/10.1016/j.carbpol.2021.118527

    Article  CAS  Google Scholar 

  11. Phanthong P, Reubroycharoen P, Kongparakul S et al (2018) Carbohydr Polym 190:184–189. https://doi.org/10.1016/j.carbpol.2018.02.066

    Article  CAS  Google Scholar 

  12. Gore PM, Naebe M, Wang X, Kandasubramanian B (2019) Chem Eng J 374:437–470. https://doi.org/10.1016/j.cej.2019.05.163

    Article  CAS  Google Scholar 

  13. Shome A, Moses JC, Rather AM, Mandal BB, Manna U (2021) ACS Appl Mater Interfaces 13:24258–24271. https://doi.org/10.1021/acsami.1c03150

    Article  CAS  Google Scholar 

  14. Peng M, Zhu Y, Li H et al (2019) Chem Eng J 373:213–226. https://doi.org/10.1016/j.cej.2019.05.013

    Article  CAS  Google Scholar 

  15. Fürtauer S, Hassan M, Elsherbiny A, Gabal SA, Mehanny S, Abushammala H (2021) Polymers 13:2739

    Article  Google Scholar 

  16. Patowary M, Pathak K, Ananthakrishnan R (2016) RSC Adv 6:73660–73667. https://doi.org/10.1039/c6ra14723b

    Article  CAS  Google Scholar 

  17. Maleki H, Whitmore L, Hüsing N (2018) J Mater Chem A 6:12598–12612. https://doi.org/10.1039/c8ta02821d

    Article  CAS  Google Scholar 

  18. Guan H, Cheng ZY, Wang XQ (2018) ACS Nano 12:10365–10373. https://doi.org/10.1021/acsnano.8b05763

    Article  CAS  Google Scholar 

  19. Guo Z, Long B, Gao S et al (2021) J Hazard Mater 402:123838. https://doi.org/10.1016/j.jhazmat.2020.123838

    Article  CAS  Google Scholar 

  20. Wu X, Lei Y, Li S et al (2021) J Hazard Mater 403:124090. https://doi.org/10.1016/j.jhazmat.2020.124090

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by Talent Foundation funded by Province and Ministry Co-construction Collaborative Innovation Center of Eco-chemical Engineering (No. STHGYX2206).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiaochen Wu.

Ethics declarations

Conflict of interest

The authors declare no competing financial interest.

Additional information

Handling Editor: Stephen Eichhorn.

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 1221 KB)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhao, S., Liu, K. & Wu, X. Composite sponges fabricated by silk fibers and alginate for efficient oil/water separation. J Mater Sci 58, 457–465 (2023). https://doi.org/10.1007/s10853-022-08030-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-022-08030-w

Navigation