Abstract
Silicon/porous carbon nanofibers wrapped by reduced graphene oxide (Si/P-CNFs@rGO) are innovatively synthesized via a convenient preparation process consisting of a simple electrospinning method followed by a carbonization process and a sequent electrodeposition. Experimental results show that silicon nanoparticles (Si NPs) are anchored on the carbon fiber with rGO tightly wrapped on the fiber surface. This rGO protective layer acting as a dual-functional enhancer could not only accommodate the volume expansion of Si but also enhance the electrical conductivity, leading to an improved electrochemical performance. The as-obtained Si/P-CNFs@rGO electrode exhibits an excellent performance, with a high reversible capacity of 1851.3 mAh g−1 at a current density of 0.2 A g−1 with almost no capacity fading up to 50th cycle, a high reversible capacity of 1217.8 mAh g−1 with an excellent coulombic efficiency (CE) of 99.0% at 0.53 A g−1 after 300 cycles, and a high discharge specific capacity of 421.5 mAh g−1 even at a high current density of 4 A g−1.
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Acknowledgements
This work was supported by the New Century Talent Support Plan of the Ministry of Education of China [Grant No. 2007NCET-07-0723], the National Natural Science Foundation of China [Grant No. 60936003], and the Aviation Science Foundation of China [Grant No. 2008ZH68002].
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Wu, C., Lin, J., Chu, R. et al. Reduced graphene oxide as a dual-functional enhancer wrapped over silicon/porous carbon nanofibers for high-performance lithium-ion battery anodes. J Mater Sci 52, 7984–7996 (2017). https://doi.org/10.1007/s10853-017-1001-1
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DOI: https://doi.org/10.1007/s10853-017-1001-1