Skip to main content
Log in

Oxidation protective glass–ceramic coating for higher manganese silicide thermoelectrics

  • Original Paper
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

In this work, a silica-based glass–ceramic coating has been deposited on higher manganese silicide (HMS) thermoelectrics in order to provide oxidation protection at high temperature (up to 600 °C). The coating showed good densification behaviour and an excellent thermomechanical and chemical compatibility with the HMS substrate, suppressing the silica scale formation on the HMS at high temperatures. The thermoelectric properties of the glass–ceramic-coated HMS showed excellent stability after oxidation at 600 °C in air for 500 h.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4

Similar content being viewed by others

References

  1. Gelbstein Y, Tunbridge J, Dixon R et al (2014) Physical, mechanical, and structural properties of highly efficient nanostructured n- and p-silicides for practical thermoelectric applications. J Electron Mater 43:1703–1711

    Article  Google Scholar 

  2. Kambe M, Jinushi T, Ishijima Z (2010) Encapsulated thermoelectric modules and compliant pads for advanced thermoelectric systems. J Electron Mater 39:1418–1421

    Article  Google Scholar 

  3. Chen L, Goto T, Tu R, Hirai T (1997) High-temperature oxidation behavior of PbTe and oxidation-resistive glass coating. In: Proceedings of the 16th International conference on thermoelectrics, pp 251–254

  4. Stefan MA, Thermoelectric material coated with a protective layer. US 20120024332 A1

  5. Dong H, Li X, Huang X, Zhou Y, Jiang W, Chen L (2013) Improved oxidation resistance of thermoelectric skutterudites coated with composite glass. Ceram Int 39:4551–4557

    Article  Google Scholar 

  6. Park YS, Thompson T, Kim Y, Salvador JR, Sakamoto JS (2015) Protective enamel coating for n- and p-type skutterudite thermoelectric materials. J Mater Sci 50:1500–1512. doi:10.1007/s10853-014-8711-4

    Article  Google Scholar 

  7. Tani J, Takahashi M, Kido H (2009) Fabrication of oxidation-resistant β-FeSi2 film on Mg2Si by RF magnetron-sputtering deposition. J Alloys Compd 488:346–349

    Article  Google Scholar 

  8. Martin HP, Ponicke A, Kluge M, Sichert I, Rost A, Conze S, Watzig K, Schilm J, Michaelis A (2016) TiOx-based thermoelectric modules: manufacturing, properties, and operational behaviour. J Electron Mater 45:1570–1575

    Article  Google Scholar 

  9. Smeacetto F, Salvo M, Ventrella A, Rizzo S, Ferraris M (2012) Durable glass-ceramic coatings for foam glass. Int J Appl Glass Sci 3:69–74

    Article  Google Scholar 

  10. Reidenbach F (1994) ASM handbook. Surface engineering. ASM International, Russell

  11. Evans HE, Taylor MP (1997) Creep relaxation and the spallation of oxide layers. Surf Coat Technol Surf 94–95:27–33

    Article  Google Scholar 

  12. Allam A, Nunes CA, Zalesak J, Record MC (2012) On the stability of the higher manganese silicides. J Alloys Compd 512:278–281

    Article  Google Scholar 

  13. Varshneya AK (2006) Fundamentals of inorganic glasses, 2nd edn. Society of Glass Technology, Sheffield

  14. Funahashi R, Matsumura Y, Barbier T et al (2015) Durability of silicide-based thermoelectric modules at high temperatures in air. J Electron Mater 44:2946–2952

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Huanpo Ning.

Ethics declarations

Conflict of Interest

The authors declare that they do not have any financial, personal, or other relevant interests that represent a conflict of interest in connection with the work submitted.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ning, H., Reece, M.J., Smeacetto, F. et al. Oxidation protective glass–ceramic coating for higher manganese silicide thermoelectrics. J Mater Sci 51, 9484–9489 (2016). https://doi.org/10.1007/s10853-016-0192-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-016-0192-1

Keywords

Navigation