Abstract
A simple, rapid, high-yielding and environmentally benign method for the conversion of esters and amides to the corresponding thio compounds was carried out using thiourea as thionating agent under solvothermal reaction. All the compounds isolated in good yields were characterized both by spectral analysis and comparing them with the authentic samples synthesized using the literature method.
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02 March 2023
This article has been retracted. Please see the Retraction Notice for more detail: https://doi.org/10.1007/s10853-023-08289-7
References
J. V. MEIZGER, IN “THIAZOLES AND THEIR BENZODERIVATIVES”, COMPREHENSIVE HETEROCYCLIC CHEMISTRY, edited by. A. R. Kartrizky, (Pergamon Press, New York, Vol 4, 1984) 235.
S. SCHEIBYE, B. S. PEDERSEN AND S. O. LAWESSON, Bull. Soc. Chim. Belg. 87 (1978) 229. For a comprehensive review of Lawesson's reagent, see: M. P. CAVA and M. L. LEVINSON, Tetrahedron 41 (1985) 5061.
D. PAQUER, S. SMADJA AND J. C. R. VIALLE, Seances Acad. Sci., Ser C 279 (1997) 529.
E. CAMPAIGN, “THE CHEMISTRY OF THE CARBONYL GROUP”, edited by S. PATAI, Chap. 17. Interscience, New York, (1966) 917.
D. C. SMITH, S. W. LEE AND P. L. FUCHS, J. Org. Chem., 59 (1997) 348.
J. J. BODINE AND M. K. KALOUSTIAN, Synth. Commun. 12 (1982) 787.
B. S. PEDERSEN AND S. O. LAWESSON, Bull. Soc. Chim. Belg. 86 (1977) 693.
Y. ISHI, T. HIRABAYASHI, H. IMAEDA AND K. ITO, Japan patent. 40 (1974) 441 [Chem. Abstr. 82 (1975)156074f].
F. FREEMAN, S. DARRICK AND H. L. KIM, J. Org. Chem. 57 (1992) 1722.
F. G. BORDWELL AND H. M. ANDERSON J. Am. Chem. Soc., 75 (1953) 4959.
K. M. L. RAI AND N. LINGANNA, Synth. Commun. 28 (1998) 4611.
C. A. MURTHY AND K. M. L. RAI, Ind. J. Chem. 26B (1987) 131.
A. HASSNER, K. M. L. RAI AND WIM DEAEN. Synth. Commun., 24 (1984) 1669.
N. LINGANNA, K. M. L. RAI AND S. SHASHIKANTH, Ind. J. Chem. 38B (1999) 1126.
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This article has been retracted. Please see the retraction notice for more detail: https://doi.org/10.1007/s10853-023-08289-7
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Aparna, E., Rai, K.M.L., Sureshbabu, M. et al. RETRACTED ARTICLE: Synthesis of thioesters and thioamides under solvothermal condition using thiourea as thionating agent. J Mater Sci 41, 1391–1393 (2006). https://doi.org/10.1007/s10853-006-7412-z
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DOI: https://doi.org/10.1007/s10853-006-7412-z