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Role of disorder-order transformation in consolidation of ceramics

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Abstract

The ordering of stacking-disordered silicon carbide prepared from the elements by high energy ball milling was investigated during sintering. A sharp increase in density in the temperature region 1700–1800°C was associated with a decrease in the disorder. Samples which had low disorder density showed a more continuous sintering behavior with temperature. Highly dense (up to 99% relative density) SiC can be obtained at 1900°C under a pressure of 70 MPa with no hold time. Similar results were observed for structurally disordered carbon with 10 at% of boron. The sintering behavior exhibited an abrupt density increase in the narrow temperature region of 1450–1600°C and was associated with disorder-order transformation.

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Authors and Affiliations

  1. Department of Materials Chemistry and the High-Tech Research Center, Ryukoku University, Seta, Otsu, 520-2194, Japan

    Yasuhiro Kodera, Takeshi Yamamoto, Naoki Toyofuku & Manshi Ohyanagi

  2. Facility for Advanced Combustion Synthesis (FACS), Department of Chemical Engineering and Materials Science, University of California, Davis, California, 95616, USA

    Zuhair A. Munir

Authors
  1. Yasuhiro Kodera
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  2. Takeshi Yamamoto
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  3. Naoki Toyofuku
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  4. Manshi Ohyanagi
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  5. Zuhair A. Munir
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Kodera, Y., Yamamoto, T., Toyofuku, N. et al. Role of disorder-order transformation in consolidation of ceramics. J Mater Sci 41, 727–732 (2006). https://doi.org/10.1007/s10853-006-6501-3

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