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Synthesis and characterization of heterobimetallic coordination polymers containing chiral nickel(II) macrocycle and silver(I) cyanide

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Abstract

Chiral coordination polymers [Ni(LR,R)Ag(CN)2](ClO4)·CH3CN (3) and [Ni(LS,S)Ag(CN)2](ClO4)·CH3CN (4) were prepared by the reaction of K[Ag(CN)2] with [Ni(LR,R)](ClO4)2 (1) and [Ni(LS,S)](ClO4)2 (2), respectively (LR,R/S,S = 1,8-di((R/S)-α-methylbenzyl)-1,3,6,8,10,13-hexaazacyclotetradecane). The polymers were characterized by elemental analysis, spectroscopy, magnetic measurement and single crystal X-ray diffraction. In 3, the nickel(II) macrocyclic complexes link two Ag(CN) −2 ions in axial position and each Ag(CN) −2 ion binds two adjacent nickel(II) ions to form a 1-D chain structure. The structure of 4 is nearly same to that of 3, except for chirality. 3 and 4 exhibit very weak antiferromagnetic couplings through the bridged Ag(CN) −2 ions within the 1-D chains (g = 2.20 and J/k B = −0.55 K for 3 and 4). The circular dichroism spectra of 3 and 4 show an enantiomeric pattern and have bisignate Cotton effects.

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References

  1. Uemura, T., Kitagawa, S.: Prussian blue nanoparticles protected by poly(vinylpyrrolidone). J. Am. Chem. Soc. 125, 7814 (2003)

    Article  CAS  Google Scholar 

  2. Beltran, L.M.C., Long, J.R.: Directed assembly of metal-cyanide cluster magnets. Acc. Chem. Res. 38, 325 (2005)

    Article  CAS  Google Scholar 

  3. Zhang, J., Lachgar, A.: Superexpanded Prussian-blue analogue with [Fe(CN)6]4−, [Nb6Cl12(CN)6]4−, and [Mn(salen)]+ as building units. J. Am. Chem. Soc. 129, 250 (2007)

    Article  CAS  Google Scholar 

  4. Deshmukh, M.M., Ohba, M., Kitagawa, S., Sakaki, S.: Absorption of CO2 and CS2 into the Hofmann-type porous coordination polymer: electrostatic versus dispersion interactions. J. Am. Chem. Soc. 135, 4840 (2013)

    Article  CAS  Google Scholar 

  5. Arcís-Castillo, Z., Muñoz-Lara, F.J., Muñoz, M.C., Aravena, D., Gaspar, A.B., Sánchez-Royo, J.F., Ruiz, E., Ohba, M., Matsuda, R., Kitagawa, S., Real, J.A.: Reversible chemisorption of sulfur dioxide in a spin crossover porous coordination polymer. Inorg. Chem. 52, 12777 (2013)

    Article  Google Scholar 

  6. Nelson, K.J., Miller, J.S.: Incorporation of substitutionally labile [VIII(CN)6]3− into Prussian blue type magnetic materials. Inorg. Chem. 47, 2526 (2008)

    Article  CAS  Google Scholar 

  7. Her, J.-H., Stephens, P.W., Kareis, C.M., Moore, J.G., Min, K.S., Park, J.-W., Bali, G., Kennon, B.S., Miller, J.S.: Anomalous non-Prussian blue structures and magnetic ordering of K2MnII[MnII(CN)6] and Rb2MnII[MnII(CN)6]. Inorg. Chem. 49, 1524 (2010)

    Article  CAS  Google Scholar 

  8. Hartman, M.R., Peterson, V.K., Liu, Y.: Neutron diffraction and neutron vibrational spectroscopy studies of hydrogen adsorption in the Prussian blue analogue Cu3[Co(CN)6]2. Chem. Mater. 18, 3221 (2006)

    Article  CAS  Google Scholar 

  9. Sato, Y., Ohkoshi, S.-I., Arai, K.-I., Tozawa, M., Hashimoto, K.: Solvatomagnetism-induced Faraday effect in a cobalt hexacyanochromate-based magnet. J. Am. Chem. Soc. 125, 14590 (2003)

    Article  CAS  Google Scholar 

  10. Kaye, S.S., Long, J.R.: Hydrogen storage in the dehydrated Prussian blue analogues M3[Co(CN)6]2 (M = Mn, Fe Co, Ni, Cu, Zn). J. Am. Chem. Soc. 127, 6506 (2005)

    Article  CAS  Google Scholar 

  11. Niel, V., Thompson, A.L., Goeta, A.E., Enachescu, C., Hauser, A., Galet, A., Muñoz, M.C., Real, J.A.: Thermal- and photoinduced spin-state switching in an unprecedented three-dimensional bimetallic coordination polymer. Chem. Eur. J. 11, 2047 (2005)

    Article  CAS  Google Scholar 

  12. Chakraborty, A., Haldar, R., Maji, T.K.: Bifunctional Co(II)–Ag(I) and Ni(II)–Ag(I) frameworks: modulation of magnetic property and CO2 uptake based on organic pillars. Cryst. Growth Des. 13, 4968 (2013)

    Article  CAS  Google Scholar 

  13. Bikas, R., Hosseini-Monfared, H., Vasylyeva, V., Sanchiz, J., Alonso, J., Barandiaran, J.M., Janiak, C.: Heteronuclear, mixed-metal Ag(I)–Mn(II) coordination polymers with bridging N-pyridinylisonicotinohydrazide ligands: synthesis, crystal structures, magnetic and photoluminescence properties. Dalton Trans. 43, 11925 (2014)

    Article  CAS  Google Scholar 

  14. Yan, Z., Li, J.-Y., Liu, T., Ni, Z.-P., Chen, Y.-C., Guo, F.-S., Tong, M.-L.: Enhanced spin-crossover behavior mediated by supramolecular cooperative interactions. Inorg. Chem. 53, 8129 (2014)

    Article  CAS  Google Scholar 

  15. Choi, H.J., Suh, M.P.: Self-assembly of molecular brick wall and molecular honeycomb from nickel(II) macrocycle and 1,3,5-benzenetricarboxylate: guest-dependent host structures. J. Am. Chem. Soc. 120, 10622 (1998)

    Article  CAS  Google Scholar 

  16. Min, K.S., Suh, M.P.: Self-assembly and selective guest binding of three-dimensional open-framework solids from macrocyclic complex as a trifunctional metal building. Chem. Eur. J. 7, 303 (2001)

    Article  CAS  Google Scholar 

  17. Ko, J.W., Min, K.S., Suh, M.P.: A hybrid consisting of coordination polymer and non covalent organic networks: a highly ordered 2-D phenol network assembled by edge-to-face π–π interactions. Inorg. Chem. 41, 2151 (2002)

    Article  CAS  Google Scholar 

  18. Shin, J.W., Son, H.J., Kim, S.K., Min, K.S.: Syntheses, crystal structures, circular dichroism, and magnetic properties of chiral dinuclear and polymeric nickel(II) compounds. Polyhedron 52, 1206 (2013)

    Article  CAS  Google Scholar 

  19. Min, K.S., Park, M.J., Ryoo, J.J.: Synthesis and chiral recognition of nickel(II) macrocyclic complex with (R)-naphthylethyleneamine pendant groups and its self-assembled framework. Chirality 25, 54 (2013)

    Article  CAS  Google Scholar 

  20. Ryoo, J.J., Shin, J.W., Dho, H.-S., Min, K.S.: Self-assembly and chiral recognition of a two-dimensional coordination polymer from a chiral nickel(II) macrocyclic complex and trimesic acid. Inorg. Chem. 49, 7232 (2010)

    Article  CAS  Google Scholar 

  21. Arvai, A.J., Nielsen, C.: ADSC Quantum-210 ADX Program. Area Detector System Corporation, Poway (1983)

    Google Scholar 

  22. Otwinowski, Z., Minor, W.: Processing of X-ray diffraction data collected in oscillation mode. In: Carter Jr, C.W., Sweet, R.M. (eds.) Methods in Enzymology: Macromolecular Crystallography, Part A, vol. 276, p. 307. Academic Press, New York (1997)

    Chapter  Google Scholar 

  23. Saint Plus, Version 6.02, Bruker Analytical X-ray, Madison (1999)

  24. SADABS, Version 2.03, Bruker AXS Inc., Madison (2000)

  25. Sheldrick, G.M.: A short history of SHELX. Acta Crystallogr. A 64, 112 (2008)

    Article  CAS  Google Scholar 

  26. Nakamoto, K.: Infrared and Raman Spectra of Inorganic and Coordination Compounds Part B, 6th edn, pp. 84–117. Wiley, New Jersey (2009)

    Google Scholar 

  27. Kahn, O.: Molecular Magnetism, pp. 251–260. VCH, New York (1993)

    Google Scholar 

  28. Oshio, H., Okamoto, H., Kikuchi, T., Ito, T.: The ferromagnetic chain system catena-(μ-CrO4-O, O′)[NiII(cyclam)]·2H2O. Inorg. Chem. 36, 3201 (1997)

    Article  CAS  Google Scholar 

  29. Monfort, M., Ribas, J., Solans, X., Font-Bardía, M.: Synthesis, crystal structures, and magnetostructural correlations in two new one-dimensional nickel(II) complexes with azido as bridging ligand. Effect of temperature. Inorg. Chem. 35, 7633 (1996)

    Article  CAS  Google Scholar 

  30. Shurdha, E., Moore, C.E., Rheingold, A.L., Miller, J.S.: Dinuclear [CoII(NCMe)5CoII(NCS)4] possessing octahedral and tetrahedral CoII sites. Inorg. Chem. 50, 10546 (2011)

    Article  CAS  Google Scholar 

  31. Atkins, P., Overton, T., Rourke, J., Weller, M., Armstrong, F.: Inorganic Chemistry, 4th edn, pp. 479–490. Oxford University Press, New York (2006)

    Google Scholar 

  32. Hawkins, C.J.: Absolute Configuration of Metal Complexes, pp. 176–209. Wiley-Interscience, New York (1971)

    Google Scholar 

Download references

Acknowledgments

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (No. 2013R1A1A2007314). X-ray crystallography at the PLS-II 2D-SMC beamline was supported in part by MEST and POSTECH.

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Authors and Affiliations

  1. Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, 702-701, Republic of Korea

    Ah Rim Jeong & Jong Hwa Jeong

  2. Beamline Department, Pohang Accelerator Laboratory/POSTECH, Pohang, 790-784, Republic of Korea

    Jong Won Shin

  3. Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, Kumamoto, 860-8555, Japan

    Shinya Hayami

  4. Department of Chemistry Education and Green-Nano Materials Research Center, Kyungpook National University, Daegu, 702-701, Republic of Korea

    Kil Sik Min

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  1. Ah Rim Jeong
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Correspondence to Jong Hwa Jeong or Kil Sik Min.

Electronic supplementary material

Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-1054750 (for 3) and 1054751 (for 4). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [Fax (internat.) +44-1223/336-033; E-mail: deposit@ccdc.cam.ac.uk]. Below is the link to the electronic supplementary material.

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Jeong, A.R., Shin, J.W., Jeong, J.H. et al. Synthesis and characterization of heterobimetallic coordination polymers containing chiral nickel(II) macrocycle and silver(I) cyanide. J Incl Phenom Macrocycl Chem 82, 145–152 (2015). https://doi.org/10.1007/s10847-015-0513-z

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