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2-Hydroxypropyl beta-cyclodextrin for the enhanced performance of dual function extraction and detection systems in complex oil environments

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Abstract

The use of 2-hydroxypropyl-β-cyclodextrin (2-HPCD) for the tandem extraction and proximity-induced energy transfer based detection of carcinogenic polycyclic aromatic hydrocarbons (PAHs) is described herein. Previous work investigated γ-cyclodextrin for this purpose, but the lower cost and reduced toxicity of 2-HPCD made it an attractive target for investigation. 2-HPCD was found to be highly efficient in the extraction of PAHs from oil samples, but was equally or slightly less efficient in promoting intra-cavity energy transfer to a high quantum yield fluorophore. The detection of PAHs via this system results in a new fluorescent signal that can be used to identify different PAHs in aqueous solution. This dual-function system can be very beneficial for oil spill remediation efforts.

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Acknowledgments

Funding is acknowledged from the Gulf of Mexico Research Initiative.

Conflict of interest

The authors declare no conflict of interest.

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Authors and Affiliations

  1. Department of Chemistry, University of Rhode Island, 51 Lower College Road, Kingston, RI, 02881, USA

    Nicole Serio, Chitapom Chanthalyma, Sean Peters & Mindy Levine

  2. Department of Chemistry, Yeshiva University, 500 W. 185th St., New York, NY, 10033, USA

    Dov Levine

Authors
  1. Nicole Serio
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  2. Chitapom Chanthalyma
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  3. Sean Peters
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  5. Mindy Levine
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Correspondence to Mindy Levine.

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Serio, N., Chanthalyma, C., Peters, S. et al. 2-Hydroxypropyl beta-cyclodextrin for the enhanced performance of dual function extraction and detection systems in complex oil environments. J Incl Phenom Macrocycl Chem 81, 341–346 (2015). https://doi.org/10.1007/s10847-014-0460-0

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