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Synthesis and characterization of substituted salicylate zirconium compounds and their catalytic activity over ε-caprolactone

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Abstract

In this study, zirconium salicylate compounds (1–6) were prepared by reaction of zirconium(IV) propoxide with 5-chlorosalicylic acid, 4-hydroxysalicylic acid, and 5-nitrosalicylic acid in 1-propanol, respectively. All these compounds (1–6) were characterized by 1H, 13C NMR, FTIR, mass spectroscopy, elemental, and thermogravimetric analyses. These compounds were tested as catalysts in polymerization of ε-caprolactone and were effective. Polycaprolactone was characterized by 1H, 13C NMR, and gel permeation chromatography. The number of salicylate ligands (bonded to zirconium atom) effects and substituents (on salicylate ligands) effects on the polymerization reactions were investigated first time by this study.

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Acknowledgments

This work was supported by the research foundation of Kocaeli University, (Project No: 2013/56).

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Authors and Affiliations

  1. Department of Chemistry, Kocaeli University, Kocaeli, 41380, Turkey

    Olcay Mert & Asgar Kayan

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  1. Olcay Mert
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  2. Asgar Kayan
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Correspondence to Asgar Kayan.

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Mert, O., Kayan, A. Synthesis and characterization of substituted salicylate zirconium compounds and their catalytic activity over ε-caprolactone. J Incl Phenom Macrocycl Chem 80, 409–416 (2014). https://doi.org/10.1007/s10847-014-0429-z

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  • DOI: https://doi.org/10.1007/s10847-014-0429-z

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