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Tetrapyridoxycalix[4]arene and its copper(II) complex: an ionic crystal engineering tecton for self-inclusion polymers

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Abstract

The crystal structures of a tetradentate pyridylcalix[4]arene ligand and its first copper(II) complex are discussed. The metal free ligand is mainly self-assembled by dipole–dipole interactions and a combination of CH–N bonds and CH–π interactions. The corresponding copper(II) perchlorate complex exhibits a self-inclusion behaviour to supramolecular zig-zag polymers.

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Scheme 1
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Authors and Affiliations

  1. Ulm University, Institute of Organic Chemistry II & Advanced Materials, Albert-Einstein-Allee 11, 89081, Ulm, Germany

    Michael Mastalerz

  2. Chemistry Department, Ruhr-University Bochum, Universitätsstr. 150, 44780, Bochum, Germany

    Iris M. Oppel, Klaus Merz & Gerald Dyker

Authors
  1. Michael Mastalerz
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  2. Iris M. Oppel
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  3. Klaus Merz
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  4. Gerald Dyker
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Corresponding authors

Correspondence to Michael Mastalerz or Gerald Dyker.

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CIF files of the crystal structure data of 1 and 2.

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Mastalerz, M., Oppel, I.M., Merz, K. et al. Tetrapyridoxycalix[4]arene and its copper(II) complex: an ionic crystal engineering tecton for self-inclusion polymers. J Incl Phenom Macrocycl Chem 64, 157–161 (2009). https://doi.org/10.1007/s10847-009-9548-3

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  • DOI: https://doi.org/10.1007/s10847-009-9548-3

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