The results of a study of Cd x Zn1–x S (0.5 ≤ x ≤ 1) films obtained by pyrolysis of an aerosol from solutions of the coordination compounds [Cd(N2H4CS)2Br2] and [Zn(N2H4CS)2Br2], both pure and doped with copper ions at concentrations of 10−6–10−4 at.%, are presented. The crystal structure of the films was studied. The optical forbidden band gap of the pure and doped films varies from 2.5 eV to 3.1 eV. The introduction of copper impurities increases the photoluminescence intensity by almost one order of magnitude.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 83, No. 6, pp. 993–995, November–December, 2016.
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Nituta, A.N., Artemova, E.S., Semenov, V.N. et al. Properties of Cd x Zn1–x S:Cu2+ (0.5 ≤ x ≤ 1) Films Deposited by Pyrolysis of Thiourea Coordination Compounds. J Appl Spectrosc 83, 1039–1041 (2017). https://doi.org/10.1007/s10812-017-0404-8
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DOI: https://doi.org/10.1007/s10812-017-0404-8