Abstract
A recent application of terahertz spectroscopy is to biochar, the agricultural charcoal produced by pyrolysis of various organic materials. Biochars simultaneously improve soil fertility and assist in carbon sequestration. Terahertz spectroscopy allows different biochars to be distinguished. However, the origin of the absorption features observed has not been clear. Given that biochar-based fertilizers are rich in aromatic compounds, we have investigated simple aromatic compounds as an approach to unravelling the complex biochar spectrum.
Similar content being viewed by others
References
R.A. Lewis, Terahertz Physics (Cambridge: Cambridge University Press, 2013).
E. Marris, Nature 442, 624 (2006).
K.Y. Chan, L. Van Zwieten, I. Meszaros, A. Downie, S. Joseph, Australian Journal of Soil Research 45, 629 (2007).
D. Woolf, J.E. Amonette, F.A. Street-Perrott, J. Lehmann, S. Joseph, Nature Communications 1, 56 (2010).
X. Han, X. Sun, C. Wang, M. Wu, D. Dong, T. Zhong, J.E. Thies, W. Wu, Scientific Reports 6, 24731 (2016).
F. Neese, Wiley Interdiscip. Rev.: Comput. Mol. Sci. 2, 73 (2012).
J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77, 3865 (1996).
M. Ernzerhof, G.E. Scuseria, J. Chem. Phys. 110, 5029 (1999).
V.N. Staroverov, G.E. Scuseria, J. Tao, J.P. Perdew, J. Chem. Phys. 119, 12129 (2003).
E.M. Pogson, J. Horvat, R.A. Lewis, S.D. Joseph, 35th International Conference on Infrared, Millimeter, and Terahertz Waves (2010).
L.M. Lepodise, J. Horvat, R.A. Lewis, 38th International Conference on Infrared, Millimeter, and Terahertz Waves (2013).
D. Solomon, et al., Geochimica et Cosmochimica Acta 71, 2285 (2007).
A. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 97, 2571 (1992).
F. Weigend, R. Ahlrichs, Phys. Chem. Chem. Phys. 7, 3297 (2005).
L.M. Lepodise, J. Horvat, R.A. Lewis, Appl. Spect. 69, 590 (2015).
L.M. Lepodise, J. Horvat, R.A. Lewis, J. Phys. Chem. A 119, 263 (2015).
Y. Chen, et al., Proc. SPIE 5411, 1 (2004).
H.B. Liu, et al., Proceedings of the IEEE 95, 1514 (2007).
Acknowledgments
This work was supported by the Australian Research Council, by the University of Wollongong, and by the Botswana International University of Science and Technology. Numerical modeling was performed at the University of Wollongong High Performance Computing Centre. We thank Stephen Joseph for the provision of biochar samples.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lepodise, L.M., Horvat, J. & Lewis, R.A. Terahertz Spectroscopy of Biochars and Related Aromatic Compounds. J Infrared Milli Terahz Waves 37, 1158–1165 (2016). https://doi.org/10.1007/s10762-016-0297-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10762-016-0297-2