Abstract
A relationship between methylene blue (MB) decomposition ability under visible light and local structure of xFe2O3·(100-x)SiO2 glass abbreviated as xFS prepared by sol-gel method was investigated by 57Fe-Mössbauer spectroscopy, X-ray diffractometry (XRD) and ultraviolet-visible light absorption spectroscopy (UV-Vis). Mössbauer spectra of xFS glass with x of 10, 30 and 50 annealed at 1000 °C for 3 h were mainly composed of a paramagnetic doublet due to fayalite (Fe2SiO4), and magnetic sextets due to magnetite (Fe3O4) or hematite (α-Fe2O3). The absorption area (A) of α-Fe2O3 gradually increased from 0.0 to 10.3 and 100 % with the increasing Fe2O3 content (x) of annealed xFS glass. A leaching test performed by 20 mL of MB aqueous solution and 40 mg of annealed 50FS glass showed that MB concentration decreased from 16.2 to 4.7 μmol L−1 after 2 h with the first order rate constant of 1.8 × 10−4 s−1. These results prove that annealed iron silicate glass containing α-Fe2O3 can decompose MB effectively under visible light irradiation.
Similar content being viewed by others
References
Fujishima, A., Honda, K.: Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37–38 (1972)
Ozaki, H., Iwamoto, S., Inoue, M.: Marked promotive effect of iron on visible-light-induced photocatalytic activities of nitrogen- and silicon-codoped titanias. J. Phys. Chem. C 111(45), 17061–17066 (2007). doi:10.1021/jp0751211
Hong, X., Wang, Z., Cai, W., Lu, F., Zhang, J., Yang, Y., Ma, N., Liu, Y.: Visible-light-activated nanoparticle photocatalyst of iodine-doped titanium dioxide. Chem. Mater. 17(6), 1548–1552 (2005). doi:10.1021/cm047891k
Kubuki, S., Iwanuma, J., Akiyama, K., Homonnay, Z., Kuzmann, E., Nishida, T.: 57Fe-Mössbauer study of iron-containing soda-lime silicate glass with COD reducing ability. Am. Inst. Phys. Conf. Proc. Ser. 1489, 41–46 (2012). doi:10.1063/1.4759472
Kubuki, S., Iwanuma, J., Akiyama, K., Homonnay, Z., Kuzmann, E., Nishida, T.: Water cleaning ability and local structure of iron containing soda-lime silicate glass. Hyperfine Interact. (2012). doi:10.1007/s10751-012-0655-y
Šepelák, V., Bégin-Colin, S., Caër, G.L.: Transformations in oxides induced by high-energy ball-milling. Dalton Trans. 41, 11927–11948 (2012). doi:10.1039/C2DT30349C
Bergmann, K., O’Konski, C.T.: A spectroscopic study of methylene blue monomer, dimer, and complexes with montmorillonite. J. Phys. Chem. 67, 2169–2177 (1963)
Dodd, C.G., Ribbe, P.H.: Soft X-ray spectroscopy of ferrous silicates. Phys. Chem. Miner. 3, 145–162 (1978)
Cabot, A., Puntes, V.F., Shevchenko, E., Yin, Y., Balcells, L., Marcus, M.A., Hughes, S.M., Alivisatos, A.P.: Vacancy coalescence during oxidation of iron nanoparticles. J. Am. Chem. Soc. 129, 34 (2007)
Tian, Y., Wu, D., Jia, X., Yu, B., Zhan, S.: Core-shell nanostructure of α-Fe2O3/Fe3O4: synthesis and photocatalysis for methyl orange. J. Nanomater. 837123, 1–5 (2011). doi:10.1155/2011/837123
Fu, X., Bei, F., Wang, X., Yang, X., Lu, L.: Surface-enhanced Raman scattering of 4-mercaptopyridine on sub-monolayers of α-Fe2O3 nanocrystals (sphere, spindle, cube). J. Raman Spectrosc. 40(9), 1290–1295 (2009)
Sahana, M.B., Sudakar, C., Setzler, G., Dixit, A.., Thakur, J.S., Lawes, G., Naik, R., Naik, V.M., Vaishnava, P.P.: Bandgap engineering by tuning particle size and crystallinity of SnO2-Fe2O3 nanocrystalline composite thin films. Appl. Phys. Lett. 93(23), 231909 (2008)
Author information
Authors and Affiliations
Corresponding author
Additional information
Proceedings of the 32nd International Conference on the Applications of the Mössbauer Effect (ICAME 2013) held in Opatija, Croatia, 1–6 September 2013.
Rights and permissions
About this article
Cite this article
Takahashi, Y., Kubuki, S., Akiyama, K. et al. Visible light activated photo-catalytic effect and local structure of iron silicate glass prepared by sol-gel method. Hyperfine Interact 226, 747–753 (2014). https://doi.org/10.1007/s10751-013-0928-0
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10751-013-0928-0