Abstract
In contrast to the conventional homogeneous kinetics, there is no conception of a simple reaction in the solid-state reaction kinetics. The geometric-probabilistic phenomenology currently in use is not adequate for describing the interplay between the chemical mechanism and the observed kinetic behaviour. An attempt is made to formulate a conception of simple reaction in the solid state as a basis for constructing kinetic models of involved reactions.
Similar content being viewed by others
References
M.E. Brown M. Maciejewski S. Vyazovkin et al. (2000) ArticleTitleComputational Aspects of Kinetic Analysis Thermochim. Acta 355 125–180 Occurrence Handle10.1016/S0040-6031(00)00443-3
F. Daniels (1955) ArticleTitleWhat is a Simple Reaction Chemical and Engineering News 33 2370–2381
B. Delmon (1969) Introduction a la Cinetique Heterogene Editions Technip Paris
A.K. Galwey M.E. Brown (2000) ArticleTitleSolid-State Decompositions – Stagnation or Progress? Journal of Thermal Analysis and Calorimetry 60 863–870 Occurrence Handle10.1023/A:1010107724523
A.K. Galwey M.E. Brown (1999) Thermal Decomposition of Ionic Solids Elsevier Amsterdam
P.L. Houston (2001) Chemical Kinetics and Reaction Dynamics McGraw-Hill New York
A. Korobov (2000) ArticleTitleDiscrete Versus Continual Description Of Solid State Reaction Dynamics from The Angle of Meaningful Simulation Discrete Dynamics in Nature and Society 4 165–179
A. Korobov (1998) ArticleTitleGeometrical Probabilities in Heterogeneous Kinetics: 60 Years of Side by Side Development Journal of mathematical chemistry 24 261–290 Occurrence Handle10.1023/A:1019135006122
T. Loertin C. Tautrrmann R.T. Kroemer et al. (2000) ArticleTitleOn the Surprising Kinetic Stability of Carbonic Acid Angewandte Chemie (International ed. in English) 39 891–894
M.M. Pavluchenko E.A. Prodan T.N. Samoseiko (1974) ArticleTitleKinetic Study of Ammonium Hydrocarbonate Thermal Decomposition by Microscopy and Gravimetry Kinetics and katalysis 15 796–798
F. Pertlik (1981) ArticleTitleVerfeinerung der Kristallstruktur des Teschemacherits Tscermaks Mineralogische und Petrographische Mitteilungen 29 67–74
E.A. Prodan (1990) Topochemistry of Crystals Minsk Nauka and Technika
E.A. Prodan M.M. Pavluchenko T.M. Samoseiko (1972) ArticleTitleThermal Decomposition of Ammonium Hydrocarbonate: The Form of Decomposition Figures Zeitschrift fur Physikalische Chemie 46 2653–2655
E.A. Prodan M.M. Pavluchenko T.M. Samoseiko (1970) ArticleTitleKinetics and Decomposition Figures in the Case of Thermal Decomposition of Ammonium Hydrocarbonate in Vacuum Proc. Acad. Nauk Belor. SSR. 2 24–33
S.H. Strogatz (1994) Nonlinear Dynamics and Chaos: With Applications to Physics, Biology, Chemistry and Engineering Addison-Wesley Reading, MA
D. Young (1966) Decomposition of Solids Pergamon Oxford
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Korobov, A. Simple Chemical Reactions in the Solid State: Towards Elaborating a Conception. Found Chem 7, 307–314 (2005). https://doi.org/10.1007/s10698-005-7326-x
Issue Date:
DOI: https://doi.org/10.1007/s10698-005-7326-x