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Simple Chemical Reactions in the Solid State: Towards Elaborating a Conception

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Abstract

In contrast to the conventional homogeneous kinetics, there is no conception of a simple reaction in the solid-state reaction kinetics. The geometric-probabilistic phenomenology currently in use is not adequate for describing the interplay between the chemical mechanism and the observed kinetic behaviour. An attempt is made to formulate a conception of simple reaction in the solid state as a basis for constructing kinetic models of involved reactions.

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References

  • M.E. Brown M. Maciejewski S. Vyazovkin et al. (2000) ArticleTitleComputational Aspects of Kinetic Analysis Thermochim. Acta 355 125–180 Occurrence Handle10.1016/S0040-6031(00)00443-3

    Article  Google Scholar 

  • F. Daniels (1955) ArticleTitleWhat is a Simple Reaction Chemical and Engineering News 33 2370–2381

    Google Scholar 

  • B. Delmon (1969) Introduction a la Cinetique Heterogene Editions Technip Paris

    Google Scholar 

  • A.K. Galwey M.E. Brown (2000) ArticleTitleSolid-State Decompositions – Stagnation or Progress? Journal of Thermal Analysis and Calorimetry 60 863–870 Occurrence Handle10.1023/A:1010107724523

    Article  Google Scholar 

  • A.K. Galwey M.E. Brown (1999) Thermal Decomposition of Ionic Solids Elsevier Amsterdam

    Google Scholar 

  • P.L. Houston (2001) Chemical Kinetics and Reaction Dynamics McGraw-Hill New York

    Google Scholar 

  • A. Korobov (2000) ArticleTitleDiscrete Versus Continual Description Of Solid State Reaction Dynamics from The Angle of Meaningful Simulation Discrete Dynamics in Nature and Society 4 165–179

    Google Scholar 

  • A. Korobov (1998) ArticleTitleGeometrical Probabilities in Heterogeneous Kinetics: 60 Years of Side by Side Development Journal of mathematical chemistry 24 261–290 Occurrence Handle10.1023/A:1019135006122

    Article  Google Scholar 

  • T. Loertin C. Tautrrmann R.T. Kroemer et al. (2000) ArticleTitleOn the Surprising Kinetic Stability of Carbonic Acid Angewandte Chemie (International ed. in English) 39 891–894

    Google Scholar 

  • M.M. Pavluchenko E.A. Prodan T.N. Samoseiko (1974) ArticleTitleKinetic Study of Ammonium Hydrocarbonate Thermal Decomposition by Microscopy and Gravimetry Kinetics and katalysis 15 796–798

    Google Scholar 

  • F. Pertlik (1981) ArticleTitleVerfeinerung der Kristallstruktur des Teschemacherits Tscermaks Mineralogische und Petrographische Mitteilungen 29 67–74

    Google Scholar 

  • E.A. Prodan (1990) Topochemistry of Crystals Minsk Nauka and Technika

    Google Scholar 

  • E.A. Prodan M.M. Pavluchenko T.M. Samoseiko (1972) ArticleTitleThermal Decomposition of Ammonium Hydrocarbonate: The Form of Decomposition Figures Zeitschrift fur Physikalische Chemie 46 2653–2655

    Google Scholar 

  • E.A. Prodan M.M. Pavluchenko T.M. Samoseiko (1970) ArticleTitleKinetics and Decomposition Figures in the Case of Thermal Decomposition of Ammonium Hydrocarbonate in Vacuum Proc. Acad. Nauk Belor. SSR. 2 24–33

    Google Scholar 

  • S.H. Strogatz (1994) Nonlinear Dynamics and Chaos: With Applications to Physics, Biology, Chemistry and Engineering Addison-Wesley Reading, MA

    Google Scholar 

  • D. Young (1966) Decomposition of Solids Pergamon Oxford

    Google Scholar 

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Korobov, A. Simple Chemical Reactions in the Solid State: Towards Elaborating a Conception. Found Chem 7, 307–314 (2005). https://doi.org/10.1007/s10698-005-7326-x

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