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Hyperspectral analysis of soil organic matter in coal mining regions using wavelets, correlations, and partial least squares regression

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Abstract

Hyperspectral estimation of soil organic matter (SOM) in coal mining regions is an important tool for enhancing fertilization in soil restoration programs. The correlation—partial least squares regression (PLSR) method effectively solves the information loss problem of correlation—multiple linear stepwise regression, but results of the correlation analysis must be optimized to improve precision. This study considers the relationship between spectral reflectance and SOM based on spectral reflectance curves of soil samples collected from coal mining regions. Based on the major absorption troughs in the 400–1006 nm spectral range, PLSR analysis was performed using 289 independent bands of the second derivative (SDR) with three levels and measured SOM values. A wavelet-correlation-PLSR (W-C-PLSR) model was then constructed. By amplifying useful information that was previously obscured by noise, the W-C-PLSR model was optimal for estimating SOM content, with smaller prediction errors in both calibration (R 2 = 0.970, root mean square error (RMSEC) = 3.10, and mean relative error (MREC) = 8.75) and validation (RMSEV = 5.85 and MREV = 14.32) analyses, as compared with other models. Results indicate that W-C-PLSR has great potential to estimate SOM in coal mining regions.

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References

  • Chang, C. W., & Laird, D. A. (2002). Near-infrared reflectance spectroscopic analysis of soil C and N. Soil Science, 167, 110–116.

    Article  CAS  Google Scholar 

  • Chang, C. W., Laird, D. A., Mausbach, M. J., & Hurburgh, C. R. J. (2001). Near-infrared reflectance spectroscopy-principal components regression analyses of soil properties. Crop Science Society of America Journal, 65, 480–490.

    Article  CAS  Google Scholar 

  • Chen, X., Liu, A. P., Wang, Z. J., & Peng, H. (2013). Corticomuscular Activity Modeling by Combining Partial Least Squares and Canonical Correlation Analysis. Journal of Applied Mathematics, 2013, 1–11.

  • Cho, M. A., Skidmore, A., Corsi, F., van Wieren, S. E., & Sobhan, I. (2007). Estimation of green grass/herb biomass from airborne hyperspectral imagery using spectral indices and partial least squares regression. International Journal of Applied Earth Observation and Geoinformation, 9, 414–424.

    Article  Google Scholar 

  • Croft, H., Kuhn, N. J., & Anderson, K. (2012). On the use of remote sensing techniques for monitoring spatio-temporal soil organic carbon dynamics in agricultural systems. Catena, 94, 64–74.

    Article  CAS  Google Scholar 

  • Demattê, J. A. M., Campos, R. C., Alves, M. C., Fiorio, P. R., & Nanni, M. R. (2004). Visible-NIR reflectance: a new approach on soil evaluation. Geoderma, 121, 95–112.

    Article  Google Scholar 

  • Demirel, N., Duzgun, S., & Emil, M. K. (2011a). Landuse change detection in a surface coal mine area using multi-temporal high-resolution satellite images. International Journal of Mining, Reclamation and Environment, 25, 342–349.

    Article  Google Scholar 

  • Demirel, N., Emil, M. K., & Duzgun, H. S. (2011b). Surface coal mine area monitoring using multi-temporal high-resolution satellite imagery. International Journal of Coal Geology, 86, 3–11.

    Article  CAS  Google Scholar 

  • Devi, O. Z., Basavaiah, K., Revanasiddappa, H. D., & Vinay, K. B. (2011). Titrimetric and spectrophotometric assay of pantoprazole in pharmaceuticals using cerium (IV) sulphate as oxidimetric agent. Journal of Analytical Chemistry, 66, 490–495.

    Article  CAS  Google Scholar 

  • Doetterl, S., Stevens, A., van Oost, K., Quine, T. A., & van Wesemael, B. (2013). Spatially-explicit regional-scale prediction of soil organic carbon stocks in cropland using environmental variables and mixed model approaches. Geoderma, 204, 31–42.

    Article  Google Scholar 

  • Erener, A. (2011). Remote sensing of vegetation health for reclaimed areas of Seyitomer open cast coal mine. International Journal of Coal Geology, 86, 20–26.

    Article  CAS  Google Scholar 

  • Farifteh, J., van der Meer, F., van der Meijde, M., & Atzberger, C. (2008). Spectral characteristics of salt-affected soils: a laboratory experiment. Geoderma, 145, 196–206.

    Article  CAS  Google Scholar 

  • Feret, J. B., Francois, C., Gitelson, A., Asner, G. P., Barry, K. M., Panigada, C., Richardson, A. D., & Jacquemoud, S. (2011). Optimizing spectral indices and chemometric analysis of leaf chemical properties using radiative transfer modelling. Remote Sensing of Environment, 115, 2742–2750.

    Article  Google Scholar 

  • Geladi, P., & Kowalski, B. R. (1986). Partial least-squares regression: a tutorial. Anal. Analytica Chemica Acta, 185, 1–17.

    Article  CAS  Google Scholar 

  • Ghiyamat, A., Shafri, H. Z. M., Mandiraji, G. A., Shariff, A. R. M., & Mansor, S. (2013). Hyperspectral discrimination of tree species with different classifications using single- and multiple-endmember. International Journal of Applied Earth Observation and Geoinformation, 23, 177–191.

    Article  Google Scholar 

  • Gmur, S., Zabowski, D., & Moskal, L. M. (2012). Hyperspectral analysis of soil nitrogen, carbon, carbonate, and organic matter using regression trees. Sensors, 12, 10639–10658.

    Article  CAS  Google Scholar 

  • Gomez, C., Lagacherie, P., & Coulouma, G. (2008). Continuum removal versus PLSR method for clay and calcium carbonate content estimation from laboratory and airborne hyperspectral measurements. Geoderma, 148, 141–148.

    Article  CAS  Google Scholar 

  • Gomez, C., Le Bissonnais, Y., Annabi, M., Bahri, H., & Raclot, D. (2013). Laboratory Vis-NIR spectroscopy as an alternative method for estimating the soil aggregate stability indexes of Mediterranean soils. Geoderma, 209, 86–97.

    Article  Google Scholar 

  • Groenigen, J. W. V., Mutters, C. S., Horwath, W. R., & Kessel, C. V. (2003). NIR and DRIFT-MIR spectrometry of soils for predicting soil and crop parameters in a flooded field. Plant and Soil, 250, 155–165.

    Article  Google Scholar 

  • Janik, L. J., Forrester, S. T., & Rawson, A. (2009). The prediction of soil chemical and physical properties from mid-infrared spectroscopy and combined partial least-squares regression and neural networks (PLS-NN) analysis. Chemometrics and Intelligent Laboratory Systems, 97, 179–188.

    Article  CAS  Google Scholar 

  • Kim, J. K., Kim, E. H., Park, I., Yu, B. R., Lim, J. D., Lee, Y. S., Lee, J. H., Kim, S. H., & Chung, I. M. (2014). Isoflavones profiling of soybean [Glycine max (L.) Merrill] germplasms and their correlations with metabolic pathways. Food Chemistry, 153, 258–264.

    Article  CAS  Google Scholar 

  • Kokaly, R. F., & Clark, R. N. (1999). Spectroscopic determination of leaf biochemistry using band-depth analysis of absorption features and stepwise multiple linear regression. Remote Sensing of Environment, 67, 267–287.

    Article  Google Scholar 

  • Krishnan, P., Alexander, J. D., Butler, B. J., & Hummel, J. W. (1980). Reflectance technique for predicting soil organic-matter. Soil Science Society of America Journal, 44, 1282–1285.

    Article  Google Scholar 

  • Liaghat, S., Ehsani, R., Mansor, S., Shafri, H. Z. M., Meon, S., Sankaran, S., & Azam, S. H. M. N. (2014). Early detection of basal stem rot disease (Ganoderma) in oil palms based on hyperspectral reflectance data using pattern recognition algorithms. International Journal of Remote Sensing, 35, 3427–3439.

    Article  Google Scholar 

  • Lin, L. X., Wang, Y. J., & Xiong, J. B. (2014). Hyperspectral extraction of soil available nitrogen in nan mountain coal waste scenic spot of Jinhuagong mine based on Enter-PLSR. Spectroscopy and Spectral Analysis, 34, 1656–1659.

    CAS  Google Scholar 

  • Liu, W., Chang, Q. R., Guo, M., Xing, D. X., & Yuan, Y. S. (2011). Extraction of first derivative spectrum features of soil organic matter via wavelet de-noising. Spectroscopy and Spectral Analysis, 31, 100–104.

    Google Scholar 

  • Nocita, M., Kooistra, L., Bachmann, M., Müller, A., Powell, M., & Weel, S. (2011). Predictions of soil surface and topsoil organic carbon content through the use of laboratory and field spectroscopy in the Albany Thicket Biome of Eastern CapeProvince of South Africa. Geoderma, 167–68, 295–302.

    Article  Google Scholar 

  • Pu, R. L. (2012). Comparing canonical correlation analysis with partial least squares regression in estimating forest leaf area index with multitemporal landsat TM imagery. GIScience & Remote Sensing, 49, 92–116.

    Article  Google Scholar 

  • Ramesh, P. J., Basavaiah, K., Devi, O. Z., Rajendraprasad, N., & Vinay, K. B. (2012). Titrimetric assay of ofloxacin in pharmaceuticals using cerium(IV) sulphate as an oxidimetric reagent. Journal of Analytical Chemistry, 67, 595–599.

    Article  CAS  Google Scholar 

  • Sebag, D., Disnar, J. R., Guillet, B., Di Giovanni, C., Verrecchia, E. P., & Durand, A. (2006). Monitoring organic matter dynamics in soil profiles by 'Rock-Eval pyrolysis': bulk characterization and quantification of degradation. European Journal of Soil Science, 57, 344–355.

    Article  CAS  Google Scholar 

  • Seely, B., Welham, C., & Blanco, J. A. (2010). Towards the application of soil organic matter as an indicator of forest ecosystem productivity: deriving thresholds, developing monitoring systems, and evaluating practices. Ecological Indicators, 10, 999–1008.

    Article  CAS  Google Scholar 

  • Singh, A., Jakubowski, A. R., Chidister, I., & Townsend, P. A. (2013). A MODIS approach to predicting stream water quality in Wisconsin. Remote Sensing of Environment, 128, 74–86.

    Article  Google Scholar 

  • Steffens, M., Kohlpaintner, M., & Buddenbaum, H. (2014). Fine spatial resolution mapping of soil organic matter quality in a Histosol profile. European Journal of Soil Science, 65, 827–839.

    Article  CAS  Google Scholar 

  • Vohland, M., & Emmerling, C. (2011). Determination of total soil organic C and hot water-extractable C from VIS-NIR soil reflectance with partial least squares regression and spectral feature selection techniques. European Journal of Soil Science, 62, 598–606.

    Article  CAS  Google Scholar 

  • Vohland, M., Besold, J., Hill, J., & Fründ, H. C. (2011). Comparing different multivariate calibration methods for the determination of soil organic carbon pools with visible to near infrared spectroscopy. Geoderma, 166, 168–205.

    Article  Google Scholar 

  • Wang, Y., Wang, F. M., Huang, J. F., Wang, X. Z., & Liu, Z. Y. (2009). Validation of artificial neural network techniques in the estimation of nitrogen concentration in rape using canopy hyperspectral reflectance data. International Journal of Remote Sensing, 30, 4493–4505.

    Article  Google Scholar 

  • Yang, H. F., & Li, J. L. (2013). Predictions of soil organic carbon using laboratory-based hyperspectral data in the northern Tianshan mountains, China. Environmental Monitoring and Assessment, 185, 3897–3908.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Administration of Surveying, Mapping, and Geo-information of China [201412016)], the Jiangsu Science and Technology Supporting Plan of China [BE2012637], the Fundamental Research Funds for the Central Universities [KYLX_1395], and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Correspondence to Yunjia Wang.

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Lin, L., Wang, Y., Teng, J. et al. Hyperspectral analysis of soil organic matter in coal mining regions using wavelets, correlations, and partial least squares regression. Environ Monit Assess 188, 97 (2016). https://doi.org/10.1007/s10661-016-5107-8

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  • DOI: https://doi.org/10.1007/s10661-016-5107-8

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