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Synthesis and Structure of Phosphanylated Bis-Triazoles as Potential Ligands for Chiral Catalysts

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Chemistry of Heterocyclic Compounds Aims and scope

Potential atropisomeric ligands, diphenylphosphane derivatives of bis-triazoles, were synthesized by direct phosphanylation of the starting bis-triazoles with chlorodiphenylphosphane. Their crystal structure was elucidated by X-ray diffractional analysis. The conformations of these compounds were modeled by DFT calculations.

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The authors are grateful to Prof. Uwe Manthe and Dr. Thorsten Tönsing of Bielefeld University, Germany, for providing access to computer cluster and GAUSSIAN-03 and TURBOMOLE software, as well as for technical support of calculations.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmans’ka St., Kyiv, 02094, Ukraine

    A. A. Kirilchuk, A. A. Yurchenko, Yu. G. Vlasenko, A. N. Kostyuk & A. B. Rozhenko

  2. Bielefeld University, 25 Universitätsstraße, Bielefeld, D-33615, Germany

    A. B. Rozhenko

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  1. A. A. Kirilchuk
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  2. A. A. Yurchenko
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  3. Yu. G. Vlasenko
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  4. A. N. Kostyuk
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  5. A. B. Rozhenko
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Correspondence to A. B. Rozhenko.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1697-1705, November, 2014.

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Kirilchuk, A.A., Yurchenko, A.A., Vlasenko, Y.G. et al. Synthesis and Structure of Phosphanylated Bis-Triazoles as Potential Ligands for Chiral Catalysts. Chem Heterocycl Comp 50, 1559–1566 (2015). https://doi.org/10.1007/s10593-014-1624-y

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  • DOI: https://doi.org/10.1007/s10593-014-1624-y

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