Abstract
Controlled synthesis of bimetallic catalysts has attracted much attention in heterogeneous catalysis because their catalytic activity depends on the size of nanoparticles and hence the methods of synthesis. In this work, one convenient method was proposed, with an aim to control the size and dispersion of bimetallic nanoparticles. In this method, Cu2+ (or Ni2+) configurational ion of hydrotalcites was used as directing reagent, which directed the position and dispersion of the final bimetallic nanoparticles by employing the metal interaction between Cu and Au as the driving force. The size, structure and composition of bimetallic nanoparticles were characterized using techniques of X-ray diffraction (XRD), nitrogen physisorption, X-ray photoelectron spectra (XPS) and scanning transmission electron microscopy (STEM). The mean size of bimetallic AuCu nanoparticles was 2.5 nm, which was 1/4 (Step-impregnation) or 1/10 (Co-impregnation) of that prepared by traditional methods. Even if the loading of Au was increased to 10 wt%, the obtained AuCu nanoparticles were still well dispersed. The catalytic activity of AuCu and AuNi nanoparticles in aerobic oxidation of benzyl alcohol was far higher than those prepared by traditional methods. The mechanism of forming bimetallic nanoparticles was investigated. It was found that the dispersion of Cu2+ (or Ni2+) and the interaction between Cu0 (or Ni0) and Au0 are two key factors affecting the dispersion of AuCu (or AuNi) nanoparticles.
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Divins NJ, Angurell I, Escudero C, Pérez-Dieste V, Llorca J (2014) Science 346:620–623
Bracey CL, Ellis PR, Hutchings GJ (2009) Chem Soc Rev 38:2231–2243
Baldizzone C, Mezzavilla S, Carvalho HWP, Meier JC, Schuppert AK, Heggen M, Galeano C, Grunwaldt J, Schüth F, Mayrhofer KJJ (2014) Angew Chem Int Ed 53:14250–14254
Paalanen P, Weckhuysen BM, Sankar M (2013) Catal Sci Technol 3:2869–2880
Fang W, Chen J, Zhang Q, Deng W, Wang Y (2011) Chem Eur J 17:1247–1256
Liu X, Wang A, Yang X, Zhang T, Mou C, Su D, Li J (2008) Chem Mater 21:410–418
Falsig H, Hvolbæk B, Kristensen IS, Jiang T, Bligaard T, Christensen CH, Nørskov JK (2008) Angew Chem 120:4913–4917
Li L, Gao Y, Li H, Zhao Y, Pei Y, Chen Z, Zeng X (2013) J Am Chem Soc 135:19336–19346
Liao F, Lo TWB, Tsang SCE (2015) ChemCatChem 7:1998–2014
Bauer JC, Mullins D, Li M, Wu Z, Payzant EA, Overbury SH, Dai S (2011) Phys Chem Chem Phys 13:2571–2581
Lu J, Low KB, Lei Y, Libera JA, Nicholls A, Stair PC, Elam JW (2014) Nat Commun 5:3264–3272
Zhong R, Sun K, Hong Y, Xu B (2014) ACS Catal 4:3982–3993
Rebelli J, Detwiler M, Ma S, Williams CT, Monnier JR (2010) J Catal 270:224–233
Barbier J, In: Ertl G, Knözinger H, Weitkamp J (Eds) (1999) Preparation of solid catalysts, Wiley-VCH Verlag GmbH
Lamy-Pitara E, Ouazzani-Benhima LEl, Barbier J (1992) Appl Catal A 81:47–65
Pieck CL, Marecot P, Barbier J (1996) Appl Catal A 143:283–298
Barbier J, Marécot P, Del Angel G, Bosch P, Boitiaux JP, Didillon B, Dominguez JM, Schifter I, Espmosa G (1994) Appl Catal A 116:179–186
Rebelli J, Rodriguez AA, Ma S, Williams CT, Monnier JR (2011) Catal Today 160:170–178
Beard KD, Borrelli D, Cramer AM, Blom D, Van Zee JW, Monnier JR (2009) ACS Nano 3:2841–2853
Ohashi M, Beard KD, Ma S, Blom DA, St-Pierre J, Van Zee JW, Monnier JR (2010) Electrochim Acta 55:7376–7384
Beard KD, Van Zee JW, Monnier JR (2009) Appl Catal B 88:185–193
Rodriguez AA, Williams CT, Monnier JR (2014) Appl Catal A 475:161–168
Jia Q, Zhao D, Tang B, Zhao N, Li H, Sang Y, Bao N, Zhang X, Xu X, Liu H (2014) J Mater Chem A 2:16292–16298
Guan Y, Zhao N, Tang B, Jia Q, Xu X, Liu H, Boughton RI (2013) Chem Commun 49:11524–11526
Hakim SH, Sener C, Alba-Rubio AC, Gostanian TM, O’Neill BJ, Ribeiro FH, Miller JT, Dumesic JA (2015) J Catal 328: 75–90
Wang H, Liu D, Xu C (2016) Catal Sci Technol 6:7137–7150
Liu P, Degirmenci V, Hensen EJM (2014) J Catal 313: 80–91
Debecker DP, Gaigneaux EM, Busca G (2009) Chem Eur J 15:3920–3935
Xu Z, Zhang J, Adebajo MO, Zhang H, Zhou C (2011) Appl Clay Sci 53:139–150
Fan G, Li F, Evans DG, Duan X (2014) Chem Soc Rev 43:7040–7066
Zope BN, Hibbitts DD, Neurock M, Davis RJ (2010) Science 330:74–78
Liu P, Guan Y, Santen RA, Li C, Hensen EJM (2011) Chem Commun 47:11540–11542
Wang J, Lang X, Zhaorigetu B, Jia M, Wang J, Guo X, Zhao J (2014) ChemCatChem 6:1737–1747
Zhao J, Yu G, Xin K, Li L, Fu T, Cui Y, Liu H, Xue N, Peng L, Ding W (2014) Appl Catal A 482:294–299
Du Y, Jin Q, Feng J, Zhang N, He Y, Li D (2015) Catal Sci Technol 5:3216–3225
Xu C, Sun J, Zhao B, Liu Q (2010) Appl Catal B 99:111–117
Liu P, Derchi M, Hensen EJM (2014) Appl Catal B 144:135–143
Pojanavaraphan C, Luengnaruemitchai A, Gulari E (2013) Appl Catal A 456:135–143
Luo M, Bian P, Zheng X (1998) Chin J Appl Chem 15:113–114
Liu J, Qiao B, Song Y, Huang Y, Liu J (2015) Chem Commun 51:15332–15335
Kirkeminde A, Spurlin S, Draxler-Sixta L, Cooper J, Ren S (2015) Angew Chem Int Ed 54:4203–4207
Wang Z, Xu C, Wang H (2014) Catal Lett 144:1919–1929
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This work was supported by projects funded by the Major Research Plan of National Natural Science Foundation of China (Program No. 91545130).
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Wang, H., Liu, N., Xu, C. et al. Directed Dispersion of Au Based Catalysts at H2 Reduction Process for Aerobic Oxidation of Benzyl Alcohol. Catal Lett 147, 547–565 (2017). https://doi.org/10.1007/s10562-016-1938-8
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DOI: https://doi.org/10.1007/s10562-016-1938-8